( p p )
3.5
3.0
2.5
2.0
1.5
1.0
10
8
6
4
2
0
05001000 2500 3500
VOLTAGE (V)
INTERNAL RESISTANCE (
Ω)
1500 2000 3000
DURATION (day)
VOLTAGE
INTERNAL RESISTANCE
Temp: 20°C
Long Term Discharge 300kΩ
(without wake-up pulse)
(+)
(-)
17 mm
+0
-1
33.5 mm
+0
-1.5
3.5
3.0
2.5
2.0
1.5
1.0
0200400600800
VOLTAGE (V)
DURATION (hour)
60°C
-30°C
20°C
-10C
60°
20°
-10°
-30°
3.5
3.0
2.5
2.0
1.5
1.0
0.5
0
0200400600 1000 140016001800
VOLTAGE (V)
800 1200
Pulse Condition: 300mA-1s
Base Load: 300kΩ
DEPTH OF DISCHARGE (mAh)
60°C 20°C -10°C -30°C
DISCHARGE CURVES (1kohm)
3
Features & Benefits
•Superior long term reliability
•High current pulse discharge capability
•Wide operating temperature (-40℃to 70℃)
•High safety and energy density
Specifications
Capacity: 1600 mAh Typical
Nominal Voltage: 3V
Weight: Approximately 17g
Dimensions
Pulse Discharge Characteristics
Discharge Curves (1kohm)
LITHIUMION/CR-2/3AZ/4.11V1 | Copyright © 2011 Panasonic Corporation of America. All Rights Reserved.
LITHIUM MANGANESE DIOXIDE
CR-2/3AZ
The data in this document is for descriptive purposes only and is not intended to make or imply any guarantee or warranty.
For more information on how Panasonic can assist you with your battery power solution needs call 877-726-2228,
visit www.panasonic.com/industrial/batteries-oem or e-mail oembatteries@us.panasonic.com
3.5
3.0
2.5
2.0
1.5
1.0
10
8
6
4
2
0
0 2500
VOLTAGE (V)
INTERNAL RESISTANCE (
Ω)
500 1000 1500 2000
DURATION (day) Estimated Data
INTERNAL RESISTANCE
VOLTAGE
Temp: 20°C
Long Term Discharge 100kΩ
(without wake-up pulse)
(+)
(-)
17 mm
+0
-1
45.5 mm
3.5
3.0
2.5
2.0
1.5
1.0
0100 400500600 1000
VOLTAGE (V)
200 300 700 800 900
DURATION (hour)
60°C
-30°C
20°C
-10°C
3.5
3.0
2.5
2.0
1.5
1.0
0
VOLTAGE (V)
60°
20°
-10°
-30°
3.5
3.0
2.5
2.0
1.5
1.0
0.5
0
0400 160020002400
VOLTAGE (V)
800 1200
Pulse Condition: 300mA-1s
Base Load: 300kΩ
DEPTH OF DISCHARGE (mAh)
60°C 20°C -10°C -30°C
Features & Benefits
•Superior long term reliability
•High current pulse discharge capability
•Wide operating temperature (-40℃to 70℃)
•High safety and energy density
Specifications
Capacity: 2400 mAh Typical
Nominal Voltage: 3V
Weight: Approximately 22g
Dimensions
Pulse Discharge Characteristics
Discharge Curves (1kohm)
LITHIUMION/CR-AG/4.11V1 | Copyright © 2011 Panasonic Corporation of America. All Rights Reserved.
For more information on how Panasonic can assist you with your battery power solution needs call 877-726-2228,
visit www.panasonic.com/industrial/batteries-oem or e-mail oembatteries@us.panasonic.com
LITHIUM MANGANESE DIOXIDE
CR-AG
The data in this document is for descriptive purposes only and is not intended to make or imply any guarantee or warranty.
3.5
3.0
2.5
2.0
1.5
1.0
10
8
6
4
2
0
05001000 2500 3500400045005000
VOLTAGE (V)
INTERNAL RESISTANCE (
Ω)
1500 2000 3000
DURATION (day)
INTERNAL RESISTANCE
Temp: 20°C
VOLTAGE
3.5
3.0
2.5
2.0
1.5
1.0
10
8
6
4
2
0
0100 400 1000 1400
VOLTAGE (V)
INTERNAL RESISTANCE (
Ω)
200 300 500 600 700 800 900 1100 1200 1300
DURATION (day)
INTERNAL RESISTANCE
Temp: 20°C
VOLTAGE
Long Term Discharge 300kΩ
(without wake-up pulse)
Long Term Discharge 30kΩ
(without wake-up pulse)
AUGUST 2005
LITHIUM HANDBOOK
This information is generally descriptive only and is not intended to make or imply any representation, guarantee or warranty with respect to any cells and batteries. Cell and battery designs/specifications
are subject to modification without notice. Contact Panasonic for the latest information.
2CR5 CR-P2
Nominal voltage (V)
Nominal capacity (mAh)
Continuous standard load (mA)
Operating temperature (C)
6
1,400
20
-40 ~ +70✻
Nominal voltage (V)
Nominal capacity (mAh)
Continuous standard load (mA)
Operating temperature (C)
6
1,400
20
-40 ~ +70*
* Please consult Panasonic for use below and above
-20°C to +60°C * Please consult Panasonic for use below and above
-20°C to +60°C
■ Dimensions(mm)
■ Specification
■ Temperature Characteristics
■ Dimensions(mm)
■ Specification
■ Temperature Characteristics
Weight:38.0g Weight:37.0g
Manganese Dioxide Lithium Cylindrical Batteries: Individual Specifications
Duration (cycle)
Pulse pattern: 900mA 3sec ON-27sec OFF
(one cycle)
60˚C
20˚C
-10˚C
-20˚C
7.0
6.0
5.0
4.0
3.0
2.0
1.0
Voltage (V)
0 400 800 1200 1600 2000 240
0
Duration (cycle)
Pulse pattern: 900mA 3sec ON-27sec OFF
(one cycle)
60˚C
20˚C
-10˚C
-20˚C
7.0
6.0
5.0
4.0
3.0
2.0
1.0
Voltage (V)
0 400 800 1200 1600 2000 240
0
AUGUST 2005
LITHIUM HANDBOOK
This information is generally descriptive only and is not intended to make or imply any representation, guarantee or warranty with respect to any cells and batteries. Cell and battery designs/specifications
are subject to modification without notice. Contact Panasonic for the latest information.
Nominal voltage (V)
Nominal capacity (mAh)
Continuous standard load (mA)
Operating temperature (C)
CR2 CR123A
17.0+0
-0.6
1.2 +0.3
-0.2
0
.7 ± 0.2
34.2+0.3
-0.4
+
3
1,550
20
-40 ~ +70*
* Please consult Panasonic for use below and above
-20°C to +60°C
* Please consult Panasonic for use below and above
-20°C to +60°C
Nominal voltage (V)
Nominal capacity (mAh)
Continuous standard load (mA)
Operating temperature (C)
■ Dimensions(mm)
Specification
Weight:11.0g
3
850
20
-40 ~ +70*
■ Dimensions(mm)
Specification
Temperature Characteristics
Weight:17.0g
Manganese Dioxide Lithium Cylindrical Batteries: Individual Specifications
Temperature Characteristics
* Please consult Panasonic for use below and above
-20°C to +60°C
0 200 400 600 800 1000 1200 1400 160
0
-10˚C
-20˚C
60˚C
20˚C
Duration (cycle)
Pulse pattern: 900mA 3sec ON-27sec OFF
(one cycle)
3.5
3.0
2.5
2.0
1.5
1.0
0.5
Voltage (V)
0 400 800 1200 1600 2000 240
0
-10˚C
-20˚C
60˚C
20˚C
Duration (cycle)
Pulse pattern: 900mA 3sec ON-27sec OFF
(one cycle)
3.5
3.0
2.5
2.0
1.5
1.0
0.5
Voltage (V)
AUGUST 2005
LITHIUM HANDBOOK
This information is generally descriptive only and is not intended to make or imply any representation, guarantee or warranty with respect to any cells and batteries. Cell and battery designs/specifications
are subject to modification without notice. Contact Panasonic for the latest information.
Nominal voltage (V)
Nominal capacity (mAh)
Continuous standard load (mA)
Operating temperature (C)
CR-V3p
+0.2
-0.4
14.1
12.5
52
28.4±0.2
14.4±0.2
20
7.0
6.5
6.0
5.5
5.0
4.5
4.0
3.5
3.0
1000mA Continuous Discharge
CR-V3 2
LR6 4
Discharge Characteristics of CR-V3p(2pc)and"AA"
Alkaline Cell (LR6,4pcs)
20˚C
-10˚C
20˚C
-10˚C
Discharge Time(min)
Voltage (V)
0 30 60 90 120 150 180 21
0
* Please consult Panasonic for use below and above
-20°C to +60°C
3
3,000
200
-40 ~ +70*
■ Dimensions(mm)
■ Specification
Weight:39.0g
Manganese Dioxide Lithium Cylindrical Batteries: Individual Specifications
Notice: The information and recommendations set forth are made in good faith and are believed to be accurate at the date of preparation.
Panasonic Industrial Company makes no warranty expressed or implied.
004-14 Page 1 of 2
Panasonic Batteries
Panasonic Industrial Company
A Division Panasonic Corporation of North America
5201 Tollview Drive, 1F-3
Rolling Meadows, IL 60008
Toll Free: 877-726-2228
Fax: 847-637-4660
Internet: www.panasonic.com/industrial/batteries-oem
e-mail: oembatteries@panasonic.com
MSDS
Material Safety Data Sheets (MSDS) are a sub-requirement of the Occupational Safety and Health Administration
(OSHA) Hazard Communication Standard, 29 CFR Subpart 1910.1200. This Hazard Communication Standard does
not apply to various subcategories including anything defined by OSHA as an "article". OSHA has defined "article" as a
manufactured item other than a fluid or particle; (i) which is formed to a specific shape or design during manufacture; (ii)
which has end use function(s) dependent in whole or in part upon its shape or design during end use; and (iii) which
under normal conditions of use does not release more than very small quantities, e.g. minute or trace amounts of a
hazardous chemical, and does not pose a physical hazard or health risk to employees.
Because all of our batteries are defined as "articles", they are exempt from the requirements of the Hazard
Communication Standard; hence a MSDS is not required.
The following components are found in a Panasonic Manganese Dioxide (CR) Lithium battery:
Cylindrical Cell Components Material Formula CAS #
Positive Electrode
Manganese Dioxide MnO
2
1313-13-9
Negative Electrode Lithium Li 7439-93-2
Electrolyte Propylene Carbonate-Solvent C
4
H
6
O
3
108-32-7
1,2 Dimethoxyethane-Solvent C
4
H
10
O
2
110-71-4
Lithium Triflate-Salt CF
3
SO
3
Li 33454-82-9
Coin Cell Components
Material Formula
Positive Electrode
Manganese Dioxide MnO
2
1313-13-9
Negative Electrode Lithium Li 7439-93-2
Electrolyte Propylene Carbonate-Solvent C
4
H
6
O
3
108-32-7
1,2 Dimethoxyethane-Solvent C
4
H
10
O
2
110-71-4
Lithium Perchlorate-Salt LiClO
4
7791-03-9
Lithium Triflate is Lithium Trifluoromethanesulfonate.
DISPOSAL
Lithium batteries are neither specifically listed nor exempted from the Federal Environmental Protection Agency (EPA)
hazardous waste regulations as promulgated by the Resource Conservation and Recovery Act (RCRA). The only metal
of possible concern in a lithium battery is lithium that is not a listed or characteristic toxic hazardous waste. Waste
lithium batteries can be considered a reactive hazardous waste if there is a significant amount of unreacted, or
unconsumed lithium remaining in the spent battery. The key to disposing of a lithium battery as a non-hazardous waste
is to guarantee that it is fully or mostly discharged. Once it is discharged it can be disposed of as non-hazardous waste.
You can dispose of a fully charged or partially discharged lithium battery as a hazardous waste after they are first
neutralized through an approved secondary treatment. The need for a secondary treatment prior to disposal is a
requirement of the U.S. Land Ban Restrictions of the Hazardous and Solid Waste Amendments of 1984. A secondary
treatment center can only receive these batteries as manifested hazardous waste. The waste code for charged lithium
Product Information Sheet
Product
:
Manganese Dioxide (CR
Type) Lithium Batteries
Applicable models/sizes: All CR type
cylindrical and coin batteries
Revision: January 1, 2014
The batteries referenced herein are exempt articles and are
not
subject to the OSHA Hazard
Communication Standard requirement. This sheet is provided as a service to our customers.
Notice: The information and recommendations set forth are made in good faith and are believed to be accurate at the date of preparation.
Panasonic Industrial Company makes no warranty expressed or implied.
004-14 Page 2 of 2
batteries is D003, reactive. In either case, button cell batteries contain so little lithium that they never qualify as a
reactive hazardous waste. These batteries are safe for disposal in the normal municipal waste stream.
Disposal of large quantities of undischarged lithium batteries should be performed by permitted, professional disposal
firms knowledgeable in Federal, State and local hazardous materials and hazardous waste transportation and disposal
requirements. As always, households are exempt from the RCRA hazardous waste guidelines.
In California, packages that contain CR lithium coin cells and the Owners/Operating Instructions of products that
contain CR lithium coin cells must include the following statement: “Perchlorate Material – special handling may apply,
See www.dtsc.ca.gov/hazardouswaste/perchorate”. The effective date for this Perchlorate label was July 1, 2006 for
non-consumer products and January 1, 2007 for consumer products.
TRANSPORTATION
All Panasonic lithium batteries are not subject to the requirements of the Department of Transportation (DOT)
Subchapter C, Hazardous Materials Regulations if shipped in compliance with 49 CFR 173.185 and Special
Provision 188.
Effective January 1, 2014 all Panasonic lithium batteries can be shipped by air in accordance with International Civil
Aviation Organization (ICAO), 2013-2014 edition, Section II or Section 1B or International Air Transport Association
(IATA) 55th
edition, Section II or Section 1B Packing Instructions (PI) 968 (Batteries), PI 969 (Batteries, packed with
equipment) and PI 970 (Batteries, contained in equipment) as appropriate
All Panasonic lithium batteries are regulated by the International Maritime Organization (IMO), 2012, 36
th
amendment, under Special Provisions 188 and 230.
All Panasonic lithium cells are tested and comply with the UN Model Regulations, Manual of Test and Criteria, Part
III, subsection 38.3..
If you build any of our lithium cells into a battery pack, you must also assure that they are tested in accordance with
the UN Model Regulations, Manual of Test and Criteria. Part III, subsection 38.3, 5
th
revised edition, Amendment 1.
The DOT requires that the outside of each package that contains lithium metal batteries, regardless of size or
number of batteries, be labeled with the following statement: “LITHIUM METAL BATTERIES- FORBIDDEN FOR
TRANSPORT ABOARD PASSENGER AIRCRAFT”. The labeling requirement covers shipments via highway, rail,
vessel or cargo-only aircraft and covers all shipments inside, into or out of the US. The label must be in contrasting
color and the letters must be 12 mm (0.5 in) in height for packages weighing more than 30 Kg and 6 mm (0.25 in) in
height for packages weighting less than 30 Kg.
If you plan on transporting any untested prototype battery packs contact your Panasonic Sales Representative for
regulatory information.
First Aid
If you get electrolyte in your eyes, flush with water for 15 minutes without rubbing and immediately contact a
physician. If you get electrolyte on your skin wash the area immediately with soap and water. If irritation continues,
contact a physician. If a battery is ingested, call the National Capital Poison Center (NCPC) at 202-625-3333
(Collect) or your local poison center immediately. Lithium coin batteries lodged in the esophagus should be
removed immediately. Leakage, chemical burns and perforation can occur within hours of ingestion.
General Recommendations
CAUTION: Risk of fire, explosion and burns. Do not recharge, crush, heat above 212
O
F (100
O
C) or incinerate.
Fire Safety
In case of fire, you can use a Class “D” fire extinguisher or other smothering agent such as Lith-X, copper powder or dry
sand. If you use water, use enough to smother the fire. Using an insufficient amount of water will only make the fire
worse. Cooling the exterior of the batteries will help prevent rupturing. Burning of these batteries will generate toxic
and corrosive lithium hydroxide fumes. Fire fighters should use self-contained breathing apparatus. Detailed
information on fighting a lithium metal battery fire can be found in Guide 138 (Substances – Water – Reactive) of the
US DOT Emergency Response Guide.
