3MTM NovecTM Flux Remover 10/09/14 Safety Data Sheet Copyright,2014,3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. Document Group: Issue Date: 20-0407-5 10/09/14 Version Number: Supercedes Date: 9.00 03/14/13 SECTION 1: Identification 1.1. Product identifier 3MTM NovecTM Flux Remover Product Identification Numbers 98-0212-3291-7, 98-0212-3328-7, 98-0212-3339-4, 98-0212-3461-6 1.2. Recommended use and restrictions on use Recommended use For Electronics Cleaning Only. Not Intended for Use as a Medical Device or Drug.., Flux Remover Restrictions on use NovecTM Aerosols are used in a wide variety of applications, including but not limited to precision cleaning of medical devices and as lubricant deposition solvents for medical devices. When the product is used for applications where the finished device is implanted into the human body, no residual Novec solvent may remain on the parts. It is highly recommended that the supporting test results and protocol be cited during FDA registration. 3M Electronics Markets Materials Division (EMMD) will not knowingly sample, support, or sell its products for incorporation in medical and pharmaceutical products and applications in which the 3M product will be temporarily or permanently implanted into humans or animals. The customer is responsible for evaluating and determining that a 3M EMMD product is suitable and appropriate for its particular use and intended application. The conditions of evaluation, selection, and use of a 3M product can vary widely and affect the use and intended application of a 3M product. Because many of these conditions are uniquely within the user's knowledge and control, it is essential that the user evaluate and determine whether the 3M product is suitable and appropriate for a particular use and intended application, and complies with all local applicable laws, regulations, standards, and guidance. 1.3. Supplier's details MANUFACTURER: DIVISION: ADDRESS: Telephone: 3M Electronics Markets Materials Division 3M Center, St. Paul, MN 55144-1000, USA 1-888-3M HELPS (1-888-364-3577) 1.4. Emergency telephone number 1-800-364-3577 or (651) 737-6501 (24 hours) SECTION 2: Hazard identification 2.1. Hazard classification Serious Eye Damage/Irritation: Category 2B. __________________________________________________________________________________________ Page 1 of 14 3MTM NovecTM Flux Remover 10/09/14 Simple Asphyxiant. Specific Target Organ Toxicity (central nervous system): Category 3. 2.2. Label elements Signal word Warning Symbols Exclamation mark | Pictograms Hazard Statements Causes eye irritation. May cause drowsiness or dizziness. May displace oxygen and cause rapid suffocation. Precautionary Statements Prevention: Avoid breathing dust/fume/gas/mist/vapors/spray. Use only outdoors or in a well-ventilated area. Wash thoroughly after handling. Response: IF INHALED: Remove person to fresh air and keep comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Call a POISON CENTER or doctor/physician if you feel unwell. Storage: Store in a well-ventilated place. Keep container tightly closed. Store locked up. Disposal: Dispose of contents/container in accordance with applicable local/regional/national/international regulations. 2.3. Hazards not otherwise classified Intentional misuse by deliberately concentrating and inhaling contents can be harmful or fatal. SECTION 3: Composition/information on ingredients Ingredient 1,2-Trans-dichloroethylene Ethyl nonafluoroisobutyl ether Ethyl nonafluorobutyl ether Methyl nonafluoroisobutyl ether Methyl nonafluorobutyl ether Carbon dioxide C.A.S. No. 156-60-5 163702-06-5 163702-05-4 163702-08-7 163702-07-6 124-38-9 % by Wt 65 - 72 6 - 16 4 - 14 3- 8 2- 7 1- 5 __________________________________________________________________________________________ Page 2 of 14 3MTM NovecTM Flux Remover 10/09/14 Isopropyl alcohol 67-63-0 1- 5 SECTION 4: First aid measures 4.1. Description of first aid measures Inhalation: Remove person to fresh air. If you feel unwell, get medical attention. Skin Contact: Wash with soap and water. If signs/symptoms develop, get medical attention. Eye Contact: Flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. If signs/symptoms persist, get medical attention. If Swallowed: Rinse mouth. If you feel unwell, get medical attention. 4.2. Most important symptoms and effects, both acute and delayed See Section 11.1. Information on toxicological effects. 4.3. Indication of any immediate medical attention and special treatment required Not applicable SECTION 5: Fire-fighting measures 5.1. Suitable extinguishing media Use a fire fighting agent suitable for the surrounding fire. 5.2. Special hazards arising from the substance or mixture Closed containers exposed to heat from fire may build pressure and explode. Exposure to extreme heat can give rise to thermal decomposition. Hazardous Decomposition or By-Products Substance Carbon monoxide Carbon dioxide Condition During Combustion During Combustion 5.3. Special protective actions for fire-fighters When fire fighting conditions are severe and total thermal decomposition of the product is possible, wear full protective clothing, including helmet, self-contained, positive pressure or pressure demand breathing apparatus, bunker coat and pants, bands around arms, waist and legs, face mask, and protective covering for exposed areas of the head. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Evacuate area. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Ventilate the area with fresh air. Refer to other sections of this SDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment. 6.2. Environmental precautions Avoid release to the environment. For larger spills, cover drains and build dikes to prevent entry into sewer systems or __________________________________________________________________________________________ Page 3 of 14 3MTM NovecTM Flux Remover 10/09/14 bodies of water. 6.3. Methods and material for containment and cleaning up If possible, seal leaking container. Place leaking containers in a well-ventilated area, preferably an operating exhaust hood, or if necessary outdoors on an impermeable surface until appropriate packaging for the leaking container or its contents is available. Contain spill. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Remember, adding an absorbent material does not remove a physical, health, or environmental hazard. Collect as much of the spilled material as possible. Place in a closed container approved for transportation by appropriate authorities. Clean up residue with an appropriate solvent selected by a qualified and authorized person. Ventilate the area with fresh air. Read and follow safety precautions on the solvent label and SDS. Seal the container. Dispose of collected material as soon as possible. SECTION 7: Handling and storage 7.1. Precautions for safe handling Do not breathe thermal decomposition products. For industrial or professional use only. Do not use in a confined area with minimal air exchange. Store work clothes separately from other clothing, food and tobacco products. Do not pierce or burn, even after use. Do not breathe dust/fume/gas/mist/vapors/spray. Do not get in eyes, on skin, or on clothing. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Avoid release to the environment. Avoid contact with oxidizing agents (eg. chlorine, chromic acid etc.) No smoking: Smoking while using this product can result in contamination of the tobacco and/or smoke and lead to the formation of hazardous decomposition products. 7.2. Conditions for safe storage including any incompatibilities Store in a well-ventilated place. Keep container tightly closed. Protect from sunlight. Do not expose to temperatures exceeding 50C/122F. Store away from heat. Store away from strong bases. Store away from oxidizing agents. SECTION 8: Exposure controls/personal protection 8.1. Control parameters Occupational exposure limits If a component is disclosed in section 3 but does not appear in the table below, an occupational exposure limit is not available for the component. Ingredient C.A.S. No. Agency Limit type Additional Comments Carbon dioxide 124-38-9 OSHA TWA:9000 mg/m3(5000 ppm) Carbon dioxide 124-38-9 ACGIH TWA:5000 ppm;STEL:30000 ppm 1,2-Trans-dichloroethylene 156-60-5 ACGIH TWA:200 ppm Ethene, 1,2-dichloro156-60-5 OSHA TWA:790 mg/m3(200 ppm) Ethyl nonafluorobutyl ether 163702-05- Manufacturer TWA(as total isomers):200 4 determined ppm Ethyl nonafluoroisobutyl ether 163702-06- Manufacturer TWA(as total isomers):200 5 determined ppm Methyl nonafluorobutyl ether 163702-07- AIHA TWA:750 ppm 6 Methyl nonafluoroisobutyl ether 163702-08- AIHA TWA:750 ppm 7 Isopropyl alcohol 67-63-0 ACGIH TWA:200 ppm;STEL:400 ppm A4: Not class. as human carcin Isopropyl alcohol 67-63-0 OSHA TWA:980 mg/m3(400 ppm) ACGIH : American Conference of Governmental Industrial Hygienists AIHA : American Industrial Hygiene Association CMRG : Chemical Manufacturer's Recommended Guidelines OSHA : United States Department of Labor - Occupational Safety and Health Administration TWA: Time-Weighted-Average __________________________________________________________________________________________ Page 4 of 14 3MTM NovecTM Flux Remover 10/09/14 STEL: Short Term Exposure Limit CEIL: Ceiling 8.2. Exposure controls 8.2.1. Engineering controls Provide appropriate local exhaust when product is heated. Do not remain in area where available oxygen may be reduced. Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure Limits and/or control dust/fume/gas/mist/vapors/spray. If ventilation is not adequate, use respiratory protection equipment. 8.2.2. Personal protective equipment (PPE) Eye/face protection Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face protection(s) are recommended: Indirect Vented Goggles Skin/hand protection Select and use gloves and/or protective clothing approved to relevant local standards to prevent skin contact based on the results of an exposure assessment. Selection should be based on use factors such as exposure levels, concentration of the substance or mixture, frequency and duration, physical challenges such as temperature extremes, and other use conditions. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible gloves/protective clothing. Gloves made from the following material(s) are recommended: Nitrile Rubber Respiratory protection An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator type(s) to reduce inhalation exposure: During heating: Use a positive pressure supplied-air respirator if there is a potential for over exposure from an uncontrolled release, exposure levels are not known, or under any other circumstances where air-purifying respirators may not provide adequate protection. Half facepiece or full facepiece air-purifying respirator suitable for organic vapors For questions about suitability for a specific application, consult with your respirator manufacturer. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Liquid General Physical Form: Aerosol Specific Physical Form: Clear, colorless liquid with slight odor. Contents under pressure. Odor, Color, Grade: No Data Available Odor threshold Not Applicable pH Not Applicable Melting point 44 C Boiling Point No flash point Flash Point No Data Available Evaporation rate Not Applicable Flammability (solid, gas) 5.9 % volume Flammable Limits(LEL) 14.5 % volume Flammable Limits(UEL) 360 mmHg [@ 25 C] [Details: Internal pressure for aerosol can Vapor Pressure is approximately 75 psig @25C] __________________________________________________________________________________________ Page 5 of 14 3MTM NovecTM Flux Remover 10/09/14 Vapor Density Density Specific Gravity Solubility in Water Solubility- non-water Partition coefficient: n-octanol/ water Autoignition temperature Decomposition temperature Viscosity Volatile Organic Compounds Percent volatile VOC Less H2O & Exempt Solvents 2.3 [@ 25 C] [Ref Std: AIR=1] 1.3 g/ml 1.3 [Ref Std: WATER=1] Slight (less than 10%) No Data Available No Data Available 408 C No Data Available 0.4 centipoise 67 % [Details: by weight] 100 % 67 % [Details: by weight] SECTION 10: Stability and reactivity 10.1. Reactivity This material may be reactive with certain agents under certain conditions - see the remaining headings in this section. 10.2. Chemical stability Stable. 10.3. Possibility of hazardous reactions Hazardous polymerization will not occur. 10.4. Conditions to avoid Heat 10.5. Incompatible materials Strong bases Strong oxidizing agents 10.6. Hazardous decomposition products Substance Hydrogen Chloride Hydrogen Fluoride Perfluoroisobutylene (PFIB) Condition At Elevated Temperatures - extreme conditions of heat At Elevated Temperatures - extreme conditions of heat At Elevated Temperatures - extreme conditions of heat Refer to section 5.2 for hazardous decomposition products during combustion. If the product is exposed to extreme condition of heat from misuse or equipment failure, toxic decomposition products that include hydrogen fluoride and perfluoroisobutylene can occur. SECTION 11: Toxicological information The information below may not be consistent with the material classification in Section 2 if specific ingredient classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be present below the threshold for labeling, an ingredient may not be available for exposure, or the data may not be relevant to the material as a whole. __________________________________________________________________________________________ Page 6 of 14 3MTM NovecTM Flux Remover 10/09/14 11.1. Information on Toxicological effects Signs and Symptoms of Exposure Based on test data and/or information on the components, this material may produce the following health effects: Inhalation: Intentional concentration and inhalation may be harmful or fatal. Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. May cause target organ effects after inhalation. Skin Contact: Mild Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, and dryness. Eye Contact: Moderate Eye Irritation: Signs/symptoms may include redness, swelling, pain, tearing, and blurred or hazy vision. Ingestion: Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea. May cause target organ effects after ingestion. Target Organ Effects: Single exposure may cause: Central Nervous System (CNS) Depression: Signs/symptoms may include headache, dizziness, drowsiness, incoordination, nausea, slowed reaction time, slurred speech, giddiness, and unconsciousness. Toxicological Data If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or the data are not sufficient for classification. Acute Toxicity Name Overall product Overall product 1,2-Trans-dichloroethylene 1,2-Trans-dichloroethylene 1,2-Trans-dichloroethylene Ethyl nonafluoroisobutyl ether Ethyl nonafluoroisobutyl ether Ethyl nonafluorobutyl ether Ethyl nonafluorobutyl ether Methyl nonafluoroisobutyl ether Methyl nonafluoroisobutyl ether Methyl nonafluorobutyl ether Route InhalationVapor(4 hr) Ingestion Dermal InhalationVapor (4 hours) Ingestion InhalationVapor (4 hours) Ingestion InhalationVapor (4 hours) Ingestion InhalationVapor (4 hours) Ingestion InhalationVapor (4 hours) Species Value No data available; calculated ATE > 50 mg/l Rabbit Rat No data available; calculated ATE > 5,000 mg/kg LD50 > 5,000 mg/kg LC50 95.6 mg/l Rat Rat LD50 7,902 mg/kg LC50 > 989 mg/l Rat Rat LD50 > 2,000 mg/kg LC50 > 989 mg/l Rat Rat LD50 > 2,000 mg/kg LC50 > 1,000 mg/l Rat Rat LD50 > 5,000 mg/kg LC50 > 1,000 mg/l __________________________________________________________________________________________ Page 7 of 14 3MTM NovecTM Flux Remover 10/09/14 Methyl nonafluorobutyl ether Isopropyl alcohol Isopropyl alcohol Isopropyl alcohol Carbon dioxide Ingestion Dermal InhalationVapor (4 hours) Ingestion InhalationGas (4 hours) Rat Rabbit Rat LD50 > 5,000 mg/kg LD50 12,870 mg/kg LC50 72.6 mg/l Rat Rat LD50 4,710 mg/kg LC50 > 53,000 ppm Species Rabbit Rabbit Rabbit Rabbit Rabbit Multiple animal species Value Minimal irritation No significant irritation No significant irritation No significant irritation No significant irritation No significant irritation Species Rabbit Rabbit Rabbit Rabbit Rabbit Rabbit Value Moderate irritant No significant irritation No significant irritation No significant irritation No significant irritation Severe irritant Species Guinea pig Guinea pig Guinea pig Guinea pig Guinea pig Value Not sensitizing Species Value ATE = acute toxicity estimate Skin Corrosion/Irritation Name 1,2-Trans-dichloroethylene Ethyl nonafluoroisobutyl ether Ethyl nonafluorobutyl ether Methyl nonafluoroisobutyl ether Methyl nonafluorobutyl ether Isopropyl alcohol Serious Eye Damage/Irritation Name 1,2-Trans-dichloroethylene Ethyl nonafluoroisobutyl ether Ethyl nonafluorobutyl ether Methyl nonafluoroisobutyl ether Methyl nonafluorobutyl ether Isopropyl alcohol Skin Sensitization Name Ethyl nonafluoroisobutyl ether Ethyl nonafluorobutyl ether Methyl nonafluoroisobutyl ether Methyl nonafluorobutyl ether Isopropyl alcohol Not sensitizing Not sensitizing Not sensitizing Not sensitizing Respiratory Sensitization Name Germ Cell Mutagenicity Name 1,2-Trans-dichloroethylene 1,2-Trans-dichloroethylene Ethyl nonafluoroisobutyl ether Ethyl nonafluoroisobutyl ether Ethyl nonafluorobutyl ether Ethyl nonafluorobutyl ether Methyl nonafluoroisobutyl ether Methyl nonafluoroisobutyl ether Methyl nonafluorobutyl ether Methyl nonafluorobutyl ether Isopropyl alcohol Isopropyl alcohol Route In Vitro In vivo In Vitro In vivo In Vitro In vivo In Vitro In vivo In Vitro In vivo In Vitro In vivo Value Not mutagenic Not mutagenic Not mutagenic Not mutagenic Not mutagenic Not mutagenic Not mutagenic Not mutagenic Not mutagenic Not mutagenic Not mutagenic Not mutagenic Carcinogenicity Name Route Species Value __________________________________________________________________________________________ Page 8 of 14 3MTM NovecTM Flux Remover 10/09/14 Isopropyl alcohol Inhalation Rat Some positive data exist, but the data are not sufficient for classification Reproductive Toxicity Reproductive and/or Developmental Effects Name Route Value Species Test Result 1,2-Trans-dichloroethylene Ingestion Not toxic to female reproduction Rat 1,2-Trans-dichloroethylene Inhalation Not toxic to female reproduction Rat 1,2-Trans-dichloroethylene Ingestion Not toxic to male reproduction Rat 1,2-Trans-dichloroethylene Inhalation Not toxic to male reproduction Rat 1,2-Trans-dichloroethylene Inhalation Rat Ethyl nonafluoroisobutyl ether Ingestion Some positive developmental data exist, but the data are not sufficient for classification Not toxic to female reproduction NOAEL 3,000 mg/kg/day NOAEL 16 mg/l NOAEL 3,000 mg/kg/day NOAEL 16 mg/l NOAEL 24 mg/l Ethyl nonafluoroisobutyl ether Inhalation Not toxic to female reproduction Rat Ethyl nonafluoroisobutyl ether Ingestion Not toxic to male reproduction Rat Ethyl nonafluoroisobutyl ether Inhalation Not toxic to male reproduction Rat Ethyl nonafluoroisobutyl ether Inhalation Rat Ethyl nonafluorobutyl ether Ingestion Some positive developmental data exist, but the data are not sufficient for classification Not toxic to female reproduction Ethyl nonafluorobutyl ether Inhalation Not toxic to female reproduction Rat Ethyl nonafluorobutyl ether Ingestion Not toxic to male reproduction Rat Ethyl nonafluorobutyl ether Inhalation Not toxic to male reproduction Rat Ethyl nonafluorobutyl ether Inhalation Rat Methyl nonafluoroisobutyl ether Ingestion Some positive developmental data exist, but the data are not sufficient for classification Not toxic to female reproduction Methyl nonafluoroisobutyl ether Inhalation Not toxic to female reproduction Rat Methyl nonafluoroisobutyl ether Ingestion Not toxic to male reproduction Rat Methyl nonafluoroisobutyl ether Inhalation Not toxic to male reproduction Rat Methyl nonafluoroisobutyl ether Inhalation Rat Methyl nonafluorobutyl ether Ingestion Some positive developmental data exist, but the data are not sufficient for classification Not toxic to female reproduction Methyl nonafluorobutyl ether Inhalation Not toxic to female reproduction Rat Methyl nonafluorobutyl ether Ingestion Not toxic to male reproduction Rat Rat Rat Rat Rat NOAEL 1,000 mg/kg/day NOAEL 260.1 mg/l NOAEL 1,000 mg/kg/day NOAEL 263.4 mg/l NOAEL 260 mg/l Exposure Duration 90 days 90 days 90 days 90 days during organogenesi s 28 days during gestation 28 days 4 weeks during gestation NOAEL 1,000 mg/kg/day NOAEL 260.1 mg/l NOAEL 1,000 mg/kg/day NOAEL 263.4 mg/l NOAEL 260 mg/l 28 days NOAEL 1,000 mg/kg/day NOAEL 129 mg/l NOAEL 1,000 mg/kg/day NOAEL 129 mg/l NOAEL 307 mg/l 28 days NOAEL 1,000 mg/kg/day NOAEL 129 mg/l NOAEL 1,000 28 days during gestation 28 days 4 weeks during gestation 1 generation 28 days 1 generation during gestation 1 generation 28 days __________________________________________________________________________________________ Page 9 of 14 3MTM NovecTM Flux Remover 10/09/14 Methyl nonafluorobutyl ether Inhalation Not toxic to male reproduction Rat Methyl nonafluorobutyl ether Inhalation Rat Isopropyl alcohol Ingestion Isopropyl alcohol Inhalation Carbon dioxide Inhalation Carbon dioxide Inhalation Some positive developmental data exist, but the data are not sufficient for classification Some positive developmental data exist, but the data are not sufficient for classification Some positive developmental data exist, but the data are not sufficient for classification Some positive male reproductive data exist, but the data are not sufficient for classification Some positive developmental data exist, but the data are not sufficient for classification mg/kg/day NOAEL 129 mg/l NOAEL 307 mg/l 1 generation during gestation Rat NOAEL 400 mg/kg/day during organogenesi s during gestation Rat LOAEL 9 mg/l Mouse LOAEL 350,000 ppm not available Rat LOAEL 60,000 ppm 24 hours Exposure Duration occupational exposure Target Organ(s) Specific Target Organ Toxicity - single exposure Name Route Target Organ(s) Value Species Test Result 1,2-Trans-dichloroethylene Inhalation central nervous system depression Human NOAEL Not available 1,2-Trans-dichloroethylene Inhalation respiratory irritation 1,2-Trans-dichloroethylene Ingestion Ethyl nonafluoroisobutyl ether Inhalation central nervous system depression cardiac sensitization Ethyl nonafluoroisobutyl ether Ethyl nonafluorobutyl ether Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification Some positive data exist, but the data are not sufficient for classification May cause drowsiness or dizziness Some positive data exist, but the data are not sufficient for classification All data are negative Inhalation cardiac sensitization Dog Ethyl nonafluorobutyl ether Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification All data are negative Methyl nonafluoroisobutyl ether Inhalation nervous system Dog Methyl nonafluoroisobutyl ether Methyl nonafluorobutyl ether Inhalation cardiac sensitization nervous system Some positive data exist, but the data are not sufficient for classification All data are negative Dog Methyl nonafluorobutyl ether Isopropyl alcohol Inhalation Inhalation Isopropyl alcohol Inhalation auditory system Isopropyl alcohol Ingestion central nervous system depression May cause drowsiness or dizziness Some positive data exist, but the data are not sufficient for classification Some positive data exist, but the data are not sufficient for classification May cause drowsiness or dizziness Human Isopropyl alcohol cardiac sensitization central nervous system depression respiratory irritation Some positive data exist, but the data are not sufficient for classification All data are negative Value Inhalation Inhalation NOAEL Not available Rat LOAEL 4,500 mg/kg NOAEL 204 mg/l not applicable NOAEL 989 mg/l NOAEL 204 mg/l 4 hours NOAEL 989 mg/l LOAEL 913 mg/l 4 hours NOAEL 913 mg/l LOAEL 913 mg/l 10 minutes NOAEL 913 mg/l NOAEL Not available NOAEL Not available 10 minutes Guinea pig NOAEL 13.4 mg/l 24 hours Human NOAEL Not available poisoning and/or abuse Species Test Result Exposure Duration Dog Rat Rat Dog Dog Human 17 minutes 17 minutes 10 minutes 10 minutes Specific Target Organ Toxicity - repeated exposure Name Route Target Organ(s) __________________________________________________________________________________________ Page 10 of 14 3MTM NovecTM Flux Remover 10/09/14 1,2-Trans-dichloroethylene Inhalation endocrine system | liver | kidney and/or bladder | respiratory system kidney and/or bladder 1,2-Trans-dichloroethylene Ingestion 1,2-Trans-dichloroethylene Ingestion blood | liver 1,2-Trans-dichloroethylene Ingestion Ethyl nonafluoroisobutyl ether Inhalation Ethyl nonafluoroisobutyl ether Inhalation Ethyl nonafluoroisobutyl ether Ingestion Ethyl nonafluoroisobutyl ether Ingestion Ethyl nonafluorobutyl ether Inhalation Ethyl nonafluorobutyl ether Inhalation Ethyl nonafluorobutyl ether Ingestion Ethyl nonafluorobutyl ether Ingestion Methyl nonafluoroisobutyl ether Inhalation heart | immune system | respiratory system liver | kidney and/or bladder | respiratory system heart | endocrine system | bone marrow | hematopoietic system | immune system | nervous system blood | liver | kidney and/or bladder heart | endocrine system | bone marrow | hematopoietic system | immune system | nervous system | respiratory system liver | kidney and/or bladder | respiratory system heart | endocrine system | bone marrow | hematopoietic system | immune system | nervous system blood | liver | kidney and/or bladder heart | endocrine system | bone marrow | hematopoietic system | immune system | nervous system | respiratory system liver Methyl nonafluoroisobutyl ether Inhalation bone, teeth, nails, and/or hair Methyl nonafluoroisobutyl ether Inhalation heart | skin | endocrine system | hematopoietic system | immune system | muscles | nervous system | eyes | kidney and/or bladder | respiratory All data are negative Rat NOAEL 16 mg/l 90 days Some positive data exist, but the data are not sufficient for classification Some positive data exist, but the data are not sufficient for classification All data are negative Rat NOAEL 2,000 mg/kg/day NOAEL 125 mg/kg/day 14 weeks 14 weeks Some positive data exist, but the data are not sufficient for classification All data are negative Rat NOAEL 2,000 mg/kg/day NOAEL 263.4 mg/l Rat NOAEL 263.4 mg/l 4 weeks Some positive data exist, but the data are not sufficient for classification All data are negative Rat NOAEL 1,000 mg/kg/day NOAEL 1,000 mg/kg/day 28 days Some positive data exist, but the data are not sufficient for classification All data are negative Rat NOAEL 263.4 mg/l 4 weeks Rat NOAEL 263.4 mg/l 4 weeks Some positive data exist, but the data are not sufficient for classification All data are negative Rat NOAEL 1,000 mg/kg/day NOAEL 1,000 mg/kg/day 28 days Some positive data exist, but the data are not sufficient for classification Some positive data exist, but the data are not sufficient for classification All data are negative Rat NOAEL 155 mg/l 13 weeks Rat NOAEL 129 mg/l 11 weeks Rat NOAEL 155 mg/l 13 weeks Rat Rat Rat Rat 14 weeks 4 weeks 28 days 28 days __________________________________________________________________________________________ Page 11 of 14 3MTM NovecTM Flux Remover 10/09/14 system endocrine system | liver Methyl nonafluoroisobutyl ether Ingestion Methyl nonafluoroisobutyl ether Ingestion Methyl nonafluorobutyl ether Inhalation Methyl nonafluorobutyl ether Inhalation bone, teeth, nails, and/or hair Methyl nonafluorobutyl ether Inhalation Methyl nonafluorobutyl ether Ingestion heart | skin | endocrine system | hematopoietic system | immune system | muscles | nervous system | eyes | kidney and/or bladder | respiratory system endocrine system | liver Methyl nonafluorobutyl ether Ingestion Isopropyl alcohol Inhalation Isopropyl alcohol Inhalation nervous system Isopropyl alcohol Ingestion kidney and/or bladder Carbon dioxide Inhalation heart | bone, teeth, nails, and/or hair | liver | nervous system | kidney and/or bladder | respiratory system heart | hematopoietic system | immune system | nervous system | eyes | kidney and/or bladder | respiratory system liver heart | hematopoietic system | immune system | nervous system | eyes | kidney and/or bladder | respiratory system kidney and/or bladder Some positive data exist, but the data are not sufficient for classification All data are negative Rat NOAEL 1,000 mg/kg/day NOAEL 1,000 mg/kg/day 28 days Some positive data exist, but the data are not sufficient for classification Some positive data exist, but the data are not sufficient for classification All data are negative Rat NOAEL 155 mg/l 13 weeks Rat NOAEL 129 mg/l 11 weeks Rat NOAEL 155 mg/l 13 weeks Some positive data exist, but the data are not sufficient for classification All data are negative Rat NOAEL 1,000 mg/kg/day NOAEL 1,000 mg/kg/day 28 days Some positive data exist, but the data are not sufficient for classification All data are negative Rat NOAEL 12.3 mg/l 24 months Rat 13 weeks Some positive data exist, but the data are not sufficient for classification Some positive data exist, but the data are not sufficient for classification Rat NOAEL 12 mg/l NOAEL 400 mg/kg/day LOAEL 60,000 ppm 166 days Rat Rat Rat 28 days 28 days 12 weeks Aspiration Hazard Name Value Please contact the address or phone number listed on the first page of the SDS for additional toxicological information on this material and/or its components. SECTION 12: Ecological information Ecotoxicological information Please contact the address or phone number listed on the first page of the SDS for additional ecotoxicological information on this material and/or its components. __________________________________________________________________________________________ Page 12 of 14 3MTM NovecTM Flux Remover 10/09/14 Chemical fate information Please contact the address or phone number listed on the first page of the SDS for additional chemical fate information on this material and/or its components. SECTION 13: Disposal considerations 13.1. Disposal methods Dispose of contents/ container in accordance with the local/regional/national/international regulations. Dispose of waste product in a permitted industrial waste facility. As a disposal alternative, incinerate in a permitted waste incineration facility. Facility must be capable of handling aerosol cans. Combustion products will include halogen acid (HCl/HF/HBr). Facility must be capable of handling halogenated materials. Empty drums/barrels/containers used for transporting and handling hazardous chemicals (chemical substances/mixtures/preparations classified as Hazardous as per applicable regulations) shall be considered, stored, treated & disposed of as hazardous wastes unless otherwise defined by applicable waste regulations. Consult with the respective regulating authorities to determine the available treatment and disposal facilities. EPA Hazardous Waste Number (RCRA): Not regulated SECTION 14: Transport Information For Transport Information, please visit http://3M.com/Transportinfo or call 1-800-364-3577 or 651-737-6501. SECTION 15: Regulatory information 15.1. US Federal Regulations Contact 3M for more information. 311/312 Hazard Categories: Fire Hazard - No Pressure Hazard - Yes Reactivity Hazard - No Immediate Hazard - Yes Delayed Hazard - No Section 313 Toxic Chemicals subject to the reporting requirements of that section and 40 CFR part 372 (EPCRA): Ingredient C.A.S. No 1,2-Trans-dichloroethylene (Ethene, 1,2dichloro-) 156-60-5 % by Wt 65 - 72 15.2. State Regulations Contact 3M for more information. 15.3. Chemical Inventories The components of this product are in compliance with the chemical notification requirements of TSCA. Contact 3M for more information. 15.4. International Regulations Contact 3M for more information. This SDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200. __________________________________________________________________________________________ Page 13 of 14 3MTM NovecTM Flux Remover 10/09/14 SECTION 16: Other information NFPA Hazard Classification Health: 3 Flammability: 1 Instability: 0 Special Hazards: None National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to be generated in significant quantities. HMIS Hazard Classification Health: 2 Flammability: 1 Physical Hazard: 0 Personal Protection: X - See PPE section. Hazardous Material Identification System (HMIS(R) III) hazard ratings are designed to inform employees of chemical hazards in the workplace. These ratings are based on the inherent properties of the material under expected conditions of normal use and are not intended for use in emergency situations. HMIS(R) III ratings are to be used with a fully implemented HMIS(R) III program. HMIS(R) is a registered mark of the American Coatings Association (ACA). Document Group: Issue Date: 20-0407-5 10/09/14 Version Number: Supercedes Date: 9.00 03/14/13 DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application. 3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the SDS available directly from 3M 3M USA SDSs are available at www.3M.com __________________________________________________________________________________________ Page 14 of 14 Mouser Electronics Authorized Distributor Click to View Pricing, Inventory, Delivery & Lifecycle Information: 3M: NOVEC FLUX REMOVER 12 OZ