Material Safety Data Sheet Revision Number: 003.0 Issue date: 05/08/2012 1. PRODUCT AND COMPANY IDENTIFICATION Product name: Product type: LOCTITE 243 THREADLOCKER 50ML Anaerobic Company address: Henkel Corporation One Henkel Way Rocky Hill, Connecticut 06067 IDH number: 1329467 Item number: 1329467 Region: United States Contact information: Telephone: 860.571.5100 MEDICAL EMERGENCY Phone: Poison Control Center 1-877-671-4608 (toll free) or 1-303-592-1711 TRANSPORT EMERGENCY Phone: CHEMTREC 1-800-424-9300 (toll free) or 1-703-527-3887 Internet: www.henkelna.com 2. HAZARDS IDENTIFICATION Physical state: Color: Odor: Liquid Blue Characteristic WARNING: EMERGENCY OVERVIEW HMIS: HEALTH: FLAMMABILITY: PHYSICAL HAZARD: Personal Protection: *2 1 1 See MSDS Section 8 CAUSES EYE IRRITATION. MAY CAUSE ALLERGIC SKIN REACTION. MAY CAUSE SKIN AND RESPIRATORY TRACT IRRITATION. Relevant routes of exposure: Skin, Inhalation, Eyes Potential Health Effects Inhalation: Skin contact: Eye contact: Ingestion: May cause respiratory tract irritation. May cause allergic skin reaction. May cause skin irritation with discomfort or rash. Contact with eyes will cause irritation. Pain and discomfort. Excess tearing. May be harmful if swallowed. Existing conditions aggravated by exposure: Eye, skin, and respiratory disorders. See Section 11 for additional toxicological information. 3. COMPOSITION / INFORMATION ON INGREDIENTS Hazardous components CAS NUMBER % Polyglycol dimethacrylate Tetramethylene dimethacrylate Adipic acid polymer with neopentylglycol, 1,4-butanediol and isononanol 2,4,6-Triallyloxy-1,3,5-triazine 2-[[2,2-bis[[(1-oxoallyl)oxy]methyl]butoxy]methyl]-2-ethyl1,3-propanediyl diacrylate Amorphous fumed silica Propanediol-1,2 Polyamide resin 1-Acetyl-2-phenylhydrazine Cumene 25852-47-5 2082-81-7 10 - 30 10 - 30 208945-12-4 10 - 30 101-37-1 5 - 10 94108-97-1 1-5 68611-44-9 57-55-6 Proprietary 114-83-0 98-82-8 1-5 1-5 1-5 0.1 - 1 0.1 - 1 IDH number: 1329467 Product name: LOCTITE 243 THREADLOCKER 50ML Page 1 of 5 4. FIRST AID MEASURES Inhalation: Move to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. If symptoms develop and persist, get medical attention. Skin contact: Wash with soap and water. Remove contaminated clothing and footwear. Wash clothing before reuse. If symptoms develop and persist, get medical attention. Eye contact: Flush with copious amounts of water, preferably, lukewarm water for at least 15 minutes, holding eyelids open all the time. Get medical attention. Ingestion: Do not induce vomiting. Keep individual calm. Get medical attention. 5. FIRE FIGHTING MEASURES Flash point: > 93 C (> 199.4 F) Autoignition temperature: Not available. Flammable/Explosive limits - lower: Not available. Flammable/Explosive limits - upper: Not available. Extinguishing media: Foam, dry chemical or carbon dioxide. Special firefighting procedures: Wear self-contained breathing apparatus and full protective clothing, such as turn-out gear. Unusual fire or explosion hazards: None Hazardous combustion products: Oxides of carbon. Oxides of sulfur. Oxides of nitrogen. Irritating organic fragments. 6. ACCIDENTAL RELEASE MEASURES Use personal protection recommended in Section 8, isolate the hazard area and deny entry to unnecessary and unprotected personnel. Environmental precautions: Do not allow product to enter sewer or waterways. Clean-up methods: Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Store in a partly filled, closed container until disposal. 7. HANDLING AND STORAGE Handling: Avoid contact with eyes, skin and clothing. Avoid breathing vapors or mists of this product. Wash thoroughly after handling. Storage: For safe storage, store at or below 38 C (100.4 F) Keep in a cool, well ventilated area away from heat, sparks and open flame. Keep container tightly closed until ready for use. For information on product shelf life contact Henkel Customer Service at (800) 243-4874. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Employers should complete an assessment of all workplaces to determine the need for, and selection of, proper exposure controls and protective equipment for each task performed. IDH number: 1329467 Product name: LOCTITE 243 THREADLOCKER 50ML Page 2 of 5 Hazardous components Polyglycol dimethacrylate Tetramethylene dimethacrylate Adipic acid polymer with neopentylglycol, 1,4butanediol and isononanol 2,4,6-Triallyloxy-1,3,5-triazine 2-[[2,2-bis[[(1-oxoallyl)oxy]methyl]butoxy]methyl]-2ethyl-1,3-propanediyl diacrylate Amorphous fumed silica ACGIH TLV OSHA PEL AIHA WEEL OTHER None None None None None None None None None None None None None None None None None None None None None 10 mg/m3 TWA Aerosol. None None None None None None None Propanediol-1,2 None None Polyamide resin 1-Acetyl-2-phenylhydrazine None None None None 50 ppm (245 mg/m3) TWA (SKIN) Cumene 50 ppm TWA None None None Engineering controls: Local exhaust ventilation is recommended when general ventilation is not sufficient to control airborne contamination. Respiratory protection: Use a NIOSH approved air-purifying respirator with an organic vapor cartridge. Eye/face protection: Safety goggles or safety glasses with side shields. Skin protection: Use impermeable gloves and protective clothing as necessary to prevent skin contact. Neoprene, Butyl-rubber, or nitrile-rubber gloves. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical state: Color: Odor: Odor threshold: pH: Vapor pressure: Boiling point/range: Melting point/ range: Specific gravity: Vapor density: Flash point: Flammable/Explosive limits - lower: Flammable/Explosive limits - upper: Autoignition temperature: Evaporation rate: Solubility in water: Partition coefficient (n-octanol/water): VOC content: Liquid Blue Characteristic Not available. Not available. < 0.1 mm hg (27 C (80.6 F)) > 149 C (> 300.2 F) Not available. 1.09 Not available. > 93 C (> 199.4 F) Not available. Not available. Not available. Not available. Slight Not available. 4.25 %; 46.4 g/l 10. STABILITY AND REACTIVITY Stability: Stable Hazardous reactions: Will not occur. Hazardous decomposition products: Oxides of carbon. Oxides of nitrogen. Oxides of sulfur. Irritating organic fragments. Incompatible materials: Strong oxidizing agents. Reducing agents. Strong alkalis. Oxygen scavengers. Other polymerization initiators. Heavy metals. Conditions to avoid: See "Handling and Storage" (Section 7) and "Incompatibility" (Section 10). IDH number: 1329467 Product name: LOCTITE 243 THREADLOCKER 50ML Page 3 of 5 11. TOXICOLOGICAL INFORMATION Hazardous components OSHA Carcinogen NTP Carcinogen IARC Carcinogen No No No No No No No No No No No No No No No No No No No No No No No No Group 2B No No No No No Polyglycol dimethacrylate Tetramethylene dimethacrylate Adipic acid polymer with neopentylglycol, 1,4-butanediol and isononanol 2,4,6-Triallyloxy-1,3,5-triazine 2-[[2,2-bis[[(1oxoallyl)oxy]methyl]butoxy]methyl]-2ethyl-1,3-propanediyl diacrylate Amorphous fumed silica Propanediol-1,2 Polyamide resin 1-Acetyl-2-phenylhydrazine Cumene Hazardous components (Specifically Regulated) Health Effects/Target Organs Polyglycol dimethacrylate Tetramethylene dimethacrylate Adipic acid polymer with neopentylglycol, 1,4-butanediol and isononanol 2,4,6-Triallyloxy-1,3,5-triazine 2-[[2,2-bis[[(1-oxoallyl)oxy]methyl]butoxy]methyl]-2-ethyl1,3-propanediyl diacrylate Amorphous fumed silica Propanediol-1,2 Polyamide resin 1-Acetyl-2-phenylhydrazine Cumene Irritant, Allergen Irritant, Allergen No Data No Target Organs No Data No Target Organs Irritant No Records Allergen, Blood, Kidney, Mutagen, Some evidence of carcinogenicity Central nervous system, Irritant, Lung 12. ECOLOGICAL INFORMATION Ecological information: Not available. 13. DISPOSAL CONSIDERATIONS Information provided is for unused product only. Recommended method of disposal: Follow all local, state, federal and provincial regulations for disposal. Hazardous waste number: Not a RCRA hazardous waste. 14. TRANSPORT INFORMATION The shipping classifications in this sections are for non-bulk packaging only (unless otherwise specified). Shipping classification may be different for bulk packaging. U.S. Department of Transportation Ground (49 CFR) Proper shipping name: Not regulated Hazard class or division: None Identification number: None Packing group: None International Air Transportation (ICAO/IATA) Proper shipping name: Hazard class or division: Identification number: Packing group: Not regulated None None None IDH number: 1329467 Product name: LOCTITE 243 THREADLOCKER 50ML Page 4 of 5 Water Transportation (IMO/IMDG) Proper shipping name: Hazard class or division: Identification number: Packing group: Not regulated None None None 15. REGULATORY INFORMATION United States Regulatory Information TSCA 8 (b) Inventory Status: TSCA 12(b) Export Notification: All components are listed or are exempt from listing on the Toxic Substances Control Act Inventory. None above reporting de minimus CERCLA/SARA Section 302 EHS: CERCLA/SARA Section 311/312: CERCLA/SARA 313: None above reporting de minimus Immediate Health, Delayed Health None above reporting de minimus California Proposition 65: This product contains a chemical known in the State of California to cause cancer. This product contains a chemical known to the State of California to cause birth defects or other reproductive harm. Canada Regulatory Information CEPA DSL/NDSL Status: WHMIS hazard class: All components are listed on or are exempt from listing on the Canadian Domestic Substances List. D.2.B 16. OTHER INFORMATION This material safety data sheet contains changes from the previous version in sections: 3, 8, 11, 15 Prepared by: Kyra Kozak Woods, Manager, Regulatory Affairs DISCLAIMER: The data contained herein are furnished for information only and are believed to be reliable. However, Henkel Corporation and its affiliates ("Henkel") does not assume responsibility for any results obtained by persons over whose methods Henkel has no control. It is the user's responsibility to determine the suitability of Henkel's products or any production methods mentioned herein for a particular purpose, and to adopt such precautions as may be advisable for the protection of property and persons against any hazards that may be involved in the handling and use of any Henkel's products. In light of the foregoing, Henkel specifically disclaims all warranties, express or implied, including warranties of merchantability and fitness for a particular purpose, arising from sale or use of Henkel's products. Henkel further disclaims any liability for consequential or incidental damages of any kind, including lost profits. IDH number: 1329467 Product name: LOCTITE 243 THREADLOCKER 50ML Page 5 of 5