Micro Battery Product Catalogue 2014 2015 EW N High Operating Temperature MS920T / MS621T(Under development) Designed with SII's unique sealing technology, "MS920T" offers a wider operating temperature range than conventional models, while maintaining the features of current MS-series. The conventional MS rechargeable batteries have an operating temperature range up to 60C. The new MS920T can operate at an even higher temperature of up to 85C. It is a great fit for devices that operate under high temperature environment, and for apparatuses that have high internal temperature. FEATURES APPLICATIONS Operating temperature range: -30C to +85C Backup power for Real Time Clock or Memory on Temperature Characteristics: Virtually no reduction Super small size power supply. in capacity at 85C temperature environment. < Examples of apparatus> er High Temperature Storage Characteristics: Higher In-Vehicle equipments, Camera, Meter, etc. ge. capacity retention ratio after 85C long term storage. * Please confirm the operating conditions, etc. with ke your contact at Seiko Instruments Inc. We would like to provide the detail characteristics of MS920T. SPECIFICATIONS Size Diameter Height Type Nominal Voltage Nominal Capacity Internal impedance MS920T 3V 6.5mAh 60 9.5mm 2.0mm 0.45g MS621T 3V 3.0mAh 80 6.8mm 2.1mm 0.23g (Under development) Weight MS920T High temperature (85C) Storage Characteristics 120 Voltage (V) Capacity retention ratio (%) 3.0 80 Storage Condition: 85 [Capacity measurement conditions] Charge: Constant current / Constant voltage max 0.2mA / 3.1V / 72hours / RT Discharge: Constant current 25uA / c.o.v.=2.0V / RT 60 40 24C 85C 2.8 2.6 2.4 20 0 [Capacity measurement conditions] Charge: Constant current / Constant voltage max 0.2mA / 3.1V / 72hours / RT Discharge: Constant current 25uA / c.o.v.=2.0V / 24 and 85 3.2 85C 100 Discharge Characteristics 3.4 2.2 0 20 40 60 Storage Period (days) 80 100 2.0 0 1 2 3 4 5 Capacity (mAh) 6 7 8 A few decades ago, we commercialized a highly reliable silver oxide battery to meet the requirement of quartz watch development. Since then, we have expanded our microbattery offering and technology to support the increased diversity in electronic products available today. This brochure introduces manganese silicon lithium rechargeable batteries, titanium silicon lithium rechargeable batteries, and reflowable capacitors. We plan to continuously develop higher performance microbatteries and widen our products lineup to keep up with our emerging technologies. Please feel free to contact us with any questions you may have. FEATURES 1. Superior leakage resistance Even a slight leakage from a battery may interfere with the connections made by the battery terminals, resulting in unstable device operation. Seiko Instruments Inc. offers micro batteries that are highly leak-resistant due to special sealing materials and processing technologies. 2. Large capacity In order to extend the operating time of devices with limited battery space, the market demands high volumetric efficiency. We offer large-capacity microbatteries developed with proprietary technology utilizing high-purity materials. 3. Stable operating voltage Carefully compounded ingredients allow each of our micro batteries to have a stable operating voltage over both a wide temperature range and depth of discharge. 4. High reliability Our micro batteries are manufactured under an integrated system featuring strict quality control, which starts with component manufacturing, through assembly and on to rigorous out-going inspection. CONTENTS MS920T/ MS621T ...................................... 2 Microbattery and Capacitor Lineup ............ 4 MS Lithium Rechargeable Battery............... 6 TS Lithium Rechargeable Battery .............. 10 Chip type Electric Double Layer Capacitor ....... 12 XH Capacitor .............................................. 14 Charging Circuit........................................... 17 CPX3225A................................................... 18 Selection Check Sheet ............................... 19 Environmental Activities .............................. 20 Precautions for Your Safety ......................... 21 3 Microbattery and Capacitor Lineup MICROBATTERY AND CAPACITOR FEATURES Chip type electric double layer capacitor : Small and thin size chip type Electric Double Layer Capacitor. XH capacitor : Pb-free reflowable capacitor made possible by a heat-resistant design. High capacity and long cycle characteristics are offered. MS lithium rechargeable battery : 3V type. Large capacity and high cycle life characteristics in a compact body with excellent overdischarge characteristics featured. TS lithium rechargeable battery : 1.5V type. Charge voltage range from 1.5V to 3.0V is supported while high reliability is achieved. Rechargeable battery and capacitor sizes *The rectangle and circles in the table show actual battery and capacitor sizes. MS621FE TS621E MS621T 2.1mm 1.8mm MS920SE TS920E MS920T MS518SE MS414GE XH414HG 1.2mm MS412FE MS614SE Height 1.4mm XH311HU XH311HG 1.1mm 0.9mm CPH3225A Chip type 3.2mm x 2.5mm 3.8mm 4.8mm 5.8mm 6.8mm 9.5mm SIZE Diameter Applications 4 Smartphone Digital still camera Tablet Video camera GPS*Car navigation system Watch Micro Battery 2014-2015 Microbattery and Capacitor Lineup Example of a recommended application circuit: for RTC backup VCC Mainpower supply VDD SCL CPU SDA RTC S-35390A INT1 INT2 MS414GE 3V/2.0mAh SSP-T7-FL MS614SE 3V/3.4mAh VCC Reference:4pF Temperature sensor * This circuit diagram is a reference example. See the data sheet of each product before using it. Example of RTC backup time, using MS414GE/MS614SE RTC used: CMOS real time clock IC S-35390A, made by Seiko Instruments Inc. Clock operating voltage: 1.1 to 5.5V, current consumption: 0.25A Crystal used: SSP-T7-FL, made by Seiko Instruments Inc. CL = 6.0pF, R1 = 65k max. 3.5 Battery voltage (V) 3.0 2.5 2.0 MS414GE 1.5 1.0 MS614SE RTC operable voltage 0.5 0.0 0 5,000 Discharge Time (hours) 10,000 One year (8,760 hours) * This graph is a rough indication. The operating time varies depending on the actual service conditions. Micro Battery 2014-2015 5 MS Lithium Rechargeable Battery 3V Type MS414GE / MS412FE / MS518SE / MS614SE / MS621FE / MS920SE FEATURES MS (Manganese Silicon) lithium rechargeable batteries, developed by Seiko Instruments Inc., use silicon oxide as the anode and a lithium manganese composite oxide as the cathode. As a result, they offer long cycle life and highly stable overdischarge characteristics. APPLICATIONS Negative cap Gasket Negative electrode * Backup power supply for memory or clock function in various types of electronic equipment for mobile communication, office automation, audio-visual equipment, mobile information equipment, etc. (smartphone, tablet, cellphone, PHS, cordless phone, fax machine, PC, video camera, digital camera, tuner, handy terminal, etc.) * Main power supply for small and slim portable equipment. Separater Positive electrode * Large discharge capacity : For high operational voltage range of 3.3V to 2.0V. * Long cycle life : Cycle life of over 100 cycles (over 50 cycles for MS414GE) under charge/discharge conditions of 3.1V to 2.0V (D.O.D.100%). * Excellent overdischarge characteristics : Continued stable capacity characteristics even after the battery is overdischarged down to 0.0V. * Operation over a wide temperature range: Operating temperature range : -20C to +60C Consult us for using the battery at a temperature beyond the above temperature range. * RoHS Compliant * Approved by UL (Underwriters Laboratories Inc.) UL File No. MH15628 Positive case SPECIFICATIONS Type Charge Voltage Nominal (Standard Voltage Charge Voltage)*6 (V) (V) Nominal Capacity (mAh)*1 Internal Impedance ()*2 Cycle Life (Time)*4 Size (mm) Standard Maximum Charge/ Discharge 100%*5 20%*5 Discharge Current D.O.D. D.O.D. Current (Continuous) (Depth of (Depth of Diameter Height *3 (mA) (mA) Discharge) Discharge) Weight (g) MS414GE 3 2.8 to 3.3 (3.1) 2.0 100 0.010 0.05 50 500 4.8 1.4 0.08 MS412FE 3 2.8 to 3.3 (3.1) 1.0 100 0.010 0.10 100 1000 4.8 1.2 0.07 MS518SE 3 2.8 to 3.3 (3.1) 3.4 60 0.010 0.15 100 1000 5.8 1.8 0.13 MS614SE 3 2.8 to 3.3 (3.1) 3.4 80 0.015 0.25 100 1000 6.8 1.4 0.17 MS621FE 3 2.8 to 3.3 (3.1) 5.5 80 0.015 0.25 100 1000 6.8 2.1 0.23 MS920SE 3 2.8 to 3.3 (3.1) 11.0 35 0.050 0.80 100 1000 9.5 2.1 0.47 *1. *2. *3. *4. *5. *6. Nominal capacity: Typical value of discharge capacity between 3.1V and 2.0V Internal impedance is measured using an AC (Alternating Current) method at the fully charged state. Maximum discharge current indicates the value of a current for approximately 50% of the nominal capacity. Cycle Life indicates the times charge/discharge is repeated for approximately 50% of the capacity values in the specification sheet. 100% and 20% are based on nominal capacity. A constant voltage charge is recommended, but due to a limit in charge current, it is necessary to insert a resistor to regulate the charge current. Please see Page 17 for resister value. Contact us for further details. If a constant current charge is required, contact us for more information. MS Lithium Rechargeable Batteries are not reflowable. Please mount them on PCB by hand soldering. 6 Micro Battery 2014-2015 MS Lithium Rechargeable Battery 3V Type DISCHARGE CHARACTERISTICS (CHARGE VOLTAGE DEPENDENCE) MS414GE MS412FE 3.5 3.5 Charge: max. 0.025mA/72 hours (CC/CV) Discharge: 10A/c.o.v. = 2.0V (CC) Charge: max. 0.05mA/60 hours (CC/CV) Discharge: 10 A/c.o.v. = 2.0V (CC) 3.0 Voltage (V) Voltage (V) 3.0 2.5 3.1V 2.0 2.0 2.8V 2.9V 3.0V 3.3V 1.5 0.0 0.5 1.0 1.5 2.5 2.0 2.8V 1.5 0.0 2.5 0.2 0.4 0.6 1.0 1.2 1.4 1.6 MS614SE MS518SE 3.5 3.5 Charge: max. 0.1mA/96 hours (CC/CV) Discharge: 15A/c.o.v. = 2.0V (CC) Charge: max. 0.06mA/72 hours (CC/CV) Discharge: 10 A/c.o.v. = 2.0V (CC) 3.0 Voltage (V) 3.0 Voltage (V) 3.0V 2.9V Capacity (mAh) Capacity (mAh) 2.5 2.0 1.5 0.0 0.5 1.0 1.5 2.0 2.5 3.0 3.1V 2.0 2.9V 3.0V 3.1V 3.3V 2.8V 3.3V 2.5 2.8V 1.5 0.0 3.5 1.0 2.9V 2.0 3.0V 3.0 4.0 Capacity (mAh) Capacity (mAh) MS621FE MS920SE 3.5 3.5 Charge: max. 0.1mA/96 hours (CC/CV) Discharge: 15A/c.o.v. = 2.0V (CC) Charge: max. 0.2mA/96 hours (CC/CV) Discharge: 50A/c.o.v. = 2.0V (CC) 3.0 3.0 3.1V 2.5 2.9V 2.0 1.5 0.0 3.3V 2.8V 2.0 Capacity (mAh) 3.1-3.3V 2.5 2.0 3.0V 4.0 Voltage (V) Voltage (V) 0.8 3.3V 3.1V 6.0 1.5 0.0 2.8V 2.0 4.0 6.0 2.9V 8.0 3.0V 10.0 12.0 Capacity (mAh) * c.o.v. : Cut off Voltage Micro Battery 2014-2015 7 MS Lithium Rechargeable Battery 3V Type CHARACTERISTICS MS614SE Charge/discharge characteristics Discharge Characteristics at Various Discharge Current 3.5 3.5 Charge: max. 0.1mA/3.1V, 96 hours (CC/CV) Discharge: respective current/c.o.v. = 1.5V (CC) 3.0 Voltage (V) Voltage (V) 3.0 2.5 2.0 1.5 1.0 0.0 10A 5A 2.5 2.0 Charge: max. 0.1mA/3.1V, 96 hours (CC/CV) Discharge: 15A/c.o.v. = 1.5V (CC) 1.0 2.0 3.0 1.5 0.0 4.0 300A 1.0 Capacity (mAh) Voltage (V) 3.0 Overdischarge Characteristics 2.0 3.0 2.5 -20C 2.0 1.5 0.0 4.0 25C 40C 1.0 1.5 0.0 3.0 20 days 1.0 Initial 100 days 2.0 Capacity (mAh) 8 3.5 Voltage (V) Voltage (V) 2.5 2.0 2.0 3.0 4.0 Floating Characteristics (60C, applied voltage 3.1V) Storage condition: respective period at 60C [Capacity measurement conditions] Charge: max. 0.1mA/3.1V, 96 hours (CC/CV) Discharge: 15A/c.o.v. = 2.0V (CC) 150 days 200 days 60C 0C Capacity (mAh) High Temperature (60C) Storage Characteristics 3.0 4.0 Discharge Temperature Characteristics Capacity (mAh) 3.5 3.0 3.0 180 days 90 days Initial 1.0 2.0 Charge: max. 0.1mA/3.1V, 96 hours, RT (CC/CV) Discharge: 15A/c.o.v. = 2.0V, respective temperature (CC) 30 days 2.0 1.5 0.0 3.5 Overdischarge: 18k discharge/respective period [Capacity measurement conditions] Charge: max. 0.1mA/3.1V, 96 hours (CC/CV) Discharge: 15 A/c.o.v. = 2.0V (CC) 2.5 50A 15A Capacity (mAh) Voltage (V) 3.5 100A Storage conditions: Each period at 60C, applied voltage 3.1V [Capacity measurement conditions] Charge: max. 0.1mA/3.1V, 96 hours (CC/CV) Discharge: 15A/c.o.v. = 2.0V (CC) 20days 2.5 Initial 150 days 200 days 2.0 60 days 80 days 3.0 4.0 1.5 0.0 1.0 100 days 40 days 60 days 80 days 2.0 3.0 4.0 Capacity (mAh) Micro Battery 2014-2015 MS Lithium Rechargeable Battery 3V Type DIMENSIONS OF STANDARD TERMINALS OF MS LITHIUM RECHARGEABLE BATTERIES 1.60.5 (Sn plated portion) 0.50.1 10.3 20.3 20.3 6.8max. MS621FE FL11E MS920SE FL27E 0 -1.0 0.50.2 0.50.2 0.50.2 20.3 0.50.2 10.3 20.3 12.8 (3.3) 1.80.5 (Sn plated portion) 1.70.5 (Sn plated portion) 2.7max. 2.8max. 2.10.5 9.5max. 6.8max. 0.150.02 2.10.2 0.150.02 5.8max. 1.80.5 (Sn plated portion) 1.60.5 (Sn plated portion) 2.50.3 +0.3 2.5 -0.5 1.8max. 2.10.4 0.10.02 2.1max. 2.20.3 0.10.02 1.750.1 0.50.1 0.50.1 10.3 1.60.5 (Sn plated portion) MS614SE FL28E MS518SE FL35E 0.50.1 0.10.02 2.20.5 1.6max. 1.65max. 1.750.1 4.8max. 4.8max. 2.20.5 20.3 0.50.1 0.50.1 20.3 10.3 0.50.1 0.50.1 0.10.02 1.750.1 10.3 MS412FE FL26E MS414GE FL26E 1.80.5 (Sn plated portion) 1.70.5 (Sn plated portion) - Units: mm - The hatched parts are tin plated (Sn: 100%). Micro Battery 2014-2015 9 TS Lithium Rechargeable Battery 1.5V Type TS920E / TS621E (Under Development) FEATURES * * * * Low-voltage rechargeable High capacity Long cycle life: at least 1000 cycles (20% D.O.D.) RoHS Compliant TS lithium rechargeable batteries are high capacity 1.5V type non-reflowable rechargeable batteries that provide sufficient discharge capacity with a charge voltage of less than 2.0V. SPECIFICATIONS Type Nominal Voltage (V) Charge Voltage*3 (V) TS920E 1.5 1.6 to 3.0 Standard Charge/ Nominal Capacity Internal (Voltage Range V) Impedance*1 Discharge Current (mA) (mAh) () Cycle Life*2 (Time) Diameter Height Weight (mm) (mm) (g) *4 TS621E (Under development) 5.5 (2.3 to 1.0) 0.05 1000 (20% D.O.D.) 9.5 2.0 6.8 2.1 0.46 100 (100% D.O.D.) 2.5 (2.3 to 1.0) 1.6 to 3.0 1.5 20 *1. Value measured using an AC (Alternating Current) method in the fully charged state. *2. Counts of charge and discharge repetition that maintains about 50% of the minimum guaranteed capacity *3. A constant voltage charge is recommended, but due to a limit in the charge current, it is necessary to insert a resistor to regulate the charge current. Please contact us for further details. If a constant current charge is required, please contact us for more information. *4. D.O.D. : Depth of Discharge TS Lithium Rechargeable Batteries are not reflowable. Please mount them on PCB by hand soldering. CHARACTERISTICS Charge/discharge characteristics TS920E 2.5 Voltage (V) 2.0 1.5 1.0 0.5 0.0 0 Charge : max. 200A/2.3V/72hr (CC/CV) Discharge : 50A/c.o.v.=0.7V (CC) 1 2 3 4 5 6 Capacity (mAh) * c.o.v. : Cut off Voltage 10 Micro Battery 2014-2015 TS Lithium Rechargeable Battery 1.5V Type CHARACTERISTICS TS920E Charge Voltage Characteristics Temperature Characteristics 7 6 6 5 5 Capacity (mAh) Capacity (mAh) 7 4 3 2 4 3 2 Charge: max. 200A/respective voltage/ 72hours (CC/CV) Discharge: 50A/c.o.v.= 1.0V (CC) 1 0 1.0 1.5 2.0 2.5 Charge: max. 200A/2.3V/ 72hours (CC/CV) Discharge: 50A/c.o.v.= 1.0V (CC) 1 0 -30 3.0 -10 High Temperature Storage Characteristics (60C) 100 100 Capacity retention ratio (%) 120 Capacity retention ratio (%) 120 80 60 Storage Condition: 60C [Capacity measurement conditions] Charge: max. 200A/2.3V/72hours (CC/CV) Discharge: 50A/c.o.v.= 1.0V (CC) 20 0 0 20 40 60 80 30 50 70 Temperature (C) Charge Voltage (V) 40 10 Float-Charge Characteristics (60C) 80 60 40 20 0 100 0 120 Storage Period (days) Storage Condition: 60C/2.3V applied [Capacity measurement conditions] Charge: max. 200A/2.3V/72hours (CC/CV) Discharge: 50A/c.o.v.= 1.0V (CC) 20 40 60 80 100 120 Float Charge Period (days) STANDARD TERMINALS TS920E FL27E 0 -1.0 0.50.2 0.50.2 20.3 12.8 2.7max. (3.3) 0.150.02 2.10.5 9.5max. 1.80.5 (Sn plated portion) 1.70.5 (Sn plated portion) - Units: mm - The hatched parts are tin plated (Sn: 100%). Micro Battery 2014-2015 11 Chip type Electric Double Layer Capacitor Pb-free reflowable CPH3225A FEATURES CPH3225A is thinnest and smallest chip-type electric double layer capacitor. The unique ceramic packaging with superior air-tightness is used. As the result, it offers leakage resistance and humidity resistance. Also, by optimizing its materials, a 1 minute rapid charge stores approximately 85% of full capacity. Its heat-resistant design allows for Pb-free reflowable SMT board attachment. * Small and thin size * Excellent leakage resistance and humidity resistance * Pb-free reflowable: Superior heat resistance (260C peak) allows reflow soldering by Pr-free solder * Long cycle Life: At least 10,000 times of charge/discharge * Simple Charging circuit (constant voltage charging) * Wide operating temperature range: Operating temperature range: -20C to +60C For use the battery at a temperature out of the above temperature range, please consult us. * RoHS Compliant APPLICATIONS Backup Power for various devices. Super small size power supply. Smartphone, Tablet, Cellphone, Personal computer, IC card, Game machine, Handy terminal, Video camera, various kinds of small appliance, etc. SPECIFICATIONS Type Maximum Use Voltage (V) Nominal Capacity (Voltage Range) Capacitance Internal Impedance* () Size(L x W x H) (mm) Weight (g) 3.3 4.6 Ah (3.3V-1.8V) 0.011F 160 3.2 x 2.5 x 0.9 0.025 CPH3225A *. Value measured using AC (Alternating Current) method at the discharged state. * Prohibition ripple charging A ripple (high frequency fluctuation of voltage) in the charge voltage extremely lowers the capacitor performance. Be sure to charge capacitors with a stable voltage. * Charge voltage The age deterioration of the capacitor depends on the charge voltage. The age deterioration is accelerated as charge voltage goes higher. * Usage environment Aging degradation of the capacitor varies depending on the usage environment (temperature and humidity). Contact us for further details. CHARACTERISTICS Charge/discharge characteristics 3.5 3.0 Voltage (V) 2.5 2.0 1.5 1.0 Charge: max. 1 mA/3.3V/2 hours (CC/CV) Discharge: 5A/c.o.v.= 0V (CC) 0.5 0.0 0 2 * c.o.v. : Cut off Voltage 12 4 6 Capacity (Ah) 8 10 Micro Battery 2014-2015 Chip type Electric Double Layer Capacitor Pb-free reflowable CHARACTERISTICS Charge Time Characteristics 100 80 60 40 Charge: max. 10mA/3.3V/ respective charge time (CC/CV) Discharge: 5A/c.o.v.= 2.0V (CC) 20 0 0 1 10 Float-Charge Characteristics (60C, 90%RH) 120 Capacity retention ratio (%) Capacity retention ratio (%) 120 100 100 80 60 40 20 0 1000 Storage condition: 60C/90%RH/3.3V applied [Capacity measurement conditions] Charge: max. 1mA/3.3V/2 hours (CC/CV) Discharge: 5A/c.o.v.= 2.0V (CC) Charge Time (minutes) 0 5 10 15 20 Float Charge Period (days) REFLOW SOLDERING CONDITIONS Reflow Profile Example The peak temperature is within five seconds. Peak temperature (C) Temperature (C) 250 200 150 Time above 200C 100 50 0 Recommended Reflow Conditions 270 0 50 100 150 200 250 260 250 240 230 220 300 0 10 20 30 40 50 60 70 Time above 200C (seconds) Time (seconds) The times of repeated reflow soldering must be two times or less. The Temperature must be measured at top of the cell. Max. 260C (within 5 seconds) DIMENSIONS CPH3225A 3.6 1.4 2.50.1 1.4 0.2 1.4 1.4 Recommended board layout (Tolerance : 0.05) 0.90.1 3.20.1 1.00.15 (0.15) 1.00.1 1.00.1 (0.15) 1.00.15 - Units: mm Micro Battery 2014-2015 13 XH Capacitor Pb-free reflowable XH311HG/XH311HU/XH414HG FEATURES * Pb-free reflowable: Superior heat resistance (260C peak) allows reflow soldering by Pb-free solder * Wide operating voltage range from 0V to 3.3V * High capacity: 0.08F with "414" size * Long Cycle Life: At least 10,000 times of charge/discharge * Simple charging circuit (constant voltage charging) * Wide operating temperature range: Operating temperature range: -20C to +60C For using the battery at a temperature out of the above temperature range, please consult us. * RoHS Compliant The XH series capacitor has a better discharge characteristic above 3V. It is an environmentally friendly product that is reflow mounted by Pb-free soldering. It features high capacity, and long-term reliability, as well as a wide operating voltage range. It is thus suitable for backup power supply of clock and memory functions on mobile and information devices. APPLICATIONS Backup power supply for memory and clock functions of smartphone, tablet, cellphone, PHS, cordless phone, digital still camera, game machine, and printer, etc. SPECIFICATIONS Electrical Specifications (Normal Temperature)*1 Maximum Use Voltage (V) Type Size Capacitance (F) Internal Impedance*2 () Diameter (mm) Height (mm) Weight (g) XH311HG 3.3 0.02 300 3.8 1.1 0.04 XH311HU 3.3 0.035 150 3.8 1.1 0.04 XH414HG 3.3 0.08 100 4.8 1.4 0.06 *1. Normal temperature: 23C 3C. Electrical characteristics and aging degradation of the products depend on temperature. *2. Value measured using AC (Alternating Current) method at the discharged state. * Prohibition ripple charging A ripple (high frequency fluctuation of voltage) in the charge voltage extremely lowers the capacitor performance. Be sure to charge capacitors with a stable voltage. * Charge voltage The age deterioration of the capacitor depends on the charge voltage. The age deterioration is accelerated as charge voltage goes higher. * Usage environment Aging degradation of the capacitor varies depending on the usage environment (temperature and humidity). Contact us for further details. CHARACTERISTICS Charge/discharge characteristics XH311HG XH311HU 3.5 Charge: max. 500A/3.3V/1hour/RT (CC/CV) Discharge: 5A/c.o.v.= 0V (CC) 2.0 1.5 1.0 5 10 1.5 1.0 Discharge 0.5 Charge: max. 500A/3.3V/5hours/RT (CC/CV) Discharge: 5A/c.o.v.= 0V (CC) 2.0 0.5 15 20 Capacity (Ah) 25 30 0.0 0 20 30 Capacity (Ah) 2.5 Charge: max. 500A/3.3V/5hours/RT (CC/CV) Discharge: 20A/c.o.v.= 0V (CC) 2.0 1.5 1.0 0.5 Discharge 10 Charge 3.0 Charge 2.5 Voltage (V) Voltage (V) 2.5 3.5 3.0 Voltage (V) Charge 3.0 0.0 0 XH414HG 3.5 40 50 0.0 0 Discharge 20 40 60 Capacity (Ah) 80 100 *c.o.v....Cut off Voltage 14 Micro Battery 2014-2015 XH Capacitor Pb-free reflowable CHARACTERISTICS XH414HG Charge Time Characteristics 35 Capacity retention ratio (%) Capacity (Ah) 30 25 20 15 10 Charge: Constant current/constant voltage max. 500A/3.3V/** hours/RT Discharge: Constant current 10A/c.o.v. = 2.0V 5 0 0 10 20 Discharge Current Characteristics 120 30 100 80 60 40 Charge: Constant current/constant voltage max. 500A/3.3V/5 hours/RT Discharge: Constant current **A/c.o.v. = 2.0V 20 0 40 0 20 Time (hours) Temperature Characteristics 60 80 100 Float-Charge Characteristics (60C, 50%RH) 120 120 100 Capacity retention ratio (%) Capacity retention ratio (%) 40 Discharge current (Ah) 80 60 40 Charge: Constant current/constant voltage max. 500A/3.3V/5 hours/RT Discharge: Constant current 10A/c.o.v. = 2.0V 20 0 -40 -20 0 20 40 60 100 80 60 Storage condition: 60C/50%RH/3.3V applied [Capacity measurement conditions] Charge: Constant current/Constant voltage max. 500A/3.3V/5hours/RT Discharge: Constant current 10A/c.o.v.= 2.0V 40 20 0 80 0 7 14 Temperature (C) 21 28 35 42 Float Charge Period (days) REFLOW SOLDERING CONDITIONS Reflow Profile Example Peak Temperature The peak temperature is within five seconds. Peak temperature (C) 250 Temperature (C) Recommended Reflow Condition 270 200 150 Time above 200C 100 50 0 0 50 100 150 200 250 300 Time (seconds) The times of repeated reflow soldering must be two times or less. The Temperature must be measured at top of the cell. Micro Battery 2014-2015 260 250 240 230 220 0 10 20 30 40 50 60 70 Time above 200C (seconds) Max.260C (within 5 seconds) 15 XH Capacitor Pb-free reflowable STANDARD TERMINALS XH311HG IV07E XH311HU IV07E 1 05 0. 4.2 1.5 2 1. 3.8max. 2.1 2.1 1.5 45 2.8 1.40.1 0.80.4 (Sn plated portion) 1.90.2 (Sn plated portion) 0.70.5 1.90.2 2.40.1 0.60.1 0.10.02 0.20.1 1.5max. Recommended board layout (Tolerance0.05) 0.9 1.90.2 0.9 1.90.2 XH414HG IV01E 45 4.1 1.7 4.8max. 2.4 2.7 5.4 6 2. 2.7 2.4 1.24 1.24 2.40.2 0.80.5 (Sn plated portion) 0.10.02 +0.1 0.2 0 2.40.2 10.5 (Sn plated portion) 2.40.2 10.1 2.40.2 3.50.1 1.670.1 Recommended board layout (Tolerance0.05) - Units: mm - The hatched parts are tin plated (Sn: 100%). 16 Micro Battery 2014-2015 Charging Circuit 1. Charging circuit for MS Lithium Rechargeable Battery Resistor to regulate the charging current Diode Vc Vo Vf Power Source Vo MS Battery Vc = Vo-Vf A resistor must be inserted to regulate the charging current, because our rechargeable batteries have a limit for charging current. Please see the below table for recommended resister values. Those values are minimum for each battery type and "Vc" in the charging circuit. The "Vc" is the actual charging voltage. Vc value is calculated by Vo-Vf, deducting Vf (forward voltage drop of the diode) from Vo (the power source voltage). For example, MS614SE and Vc 3.3V, the resister value should be 620 ohm or more. Regarding charging voltage, the actual charging voltage "Vc" must Not be higher than 3.3V. Table of minimum resistor values. Vc (V) 3.3 3.2 3.1 3.0 2.9 2.8 MS414GE MS412FE MS518SE MS614SE Resistor (ohm) 2,000 1,600 1,600 1,500 1,500 1,500 Resistor (ohm) 2,000 1,600 1,600 1,500 1,500 1,500 Resistor (ohm) 1,500 1,000 820 750 750 750 Resistor (ohm) 620 430 330 300 300 300 MS621FE MS621T Resistor (ohm) 620 430 330 300 300 300 MS920SE MS920T Resistor (ohm) 620 430 330 300 300 300 Discharge capacity depends on charging voltage (Please see Page 7) Lower than 3V charging may cause lower discharge capacity. For TS Lithium Rechargeable Battery or other batteries, please contact us. 2. Charging circuit for XH capacitor and CPH capacitor Diode Vc Vo Power Source Vo Vf XH Capacitor CPH Capacitor Vc = Vo-Vf You do not need to insert a resister to regulate charging current. Our XH capacitor or CPH capacitor do not have a limit for charging current. Please keep the limit of Maximum charging voltage, 3.3V. The "Vc" is the actual charging voltage. Vc value is calculated by Vo-Vf, deducting Vf (forward voltage drop of the diode) from Vo (the power source voltage). The actual charging voltage "Vc" must not be higher than 3.3V. This guidance is for XH capacitors and CPH capacitors. For CPX capacitor or other capacitors, please contact us. Micro Battery 2014-2015 17 Microbattery and Capacitor Selection Check Sheet Low ESR, Low leak current Chip-type EDLC CPX3225A series FEATURES APPLICATIONS Large discharge current and super rapid charging ng achieved by low internal resistance Reduced internal resistance to 25 ohms, one-third that of the conventional EDLCs, allows discharge current of up to several tens of mAs and rapid charging within a few seconds. Chargeable by slight power, thanks to low leak current Reduced leak current to about 10 nA level, approximately one-tenth that of the conventional EDLCs, allows sufficient charging with several micro ro Watts from a slight energy harvesting power source. e. Electric storage device for energy harvesting Power source or Electric storage for Wireless Sensor Network, RFID tag, RF remote control for digital home electrical appliance Power source or Electric storage for Contactless IC card, multi-functional IC card Instant back-up for CPU or DRAM and power source for saving data on flash memory SPECIFICATIONS Part number Maximum use voltage Capacitance Internal impedance Size ( L W H ) Weight CPX3225A752D 2.6V 7.5mF 25 3.2 x 2.5 x 0.9mm 0.024g CPX3225A252D 2.6V 2.5mF 25 3.2 x 2.5 x 0.9mm 0.024g (under development) 18 Micro Battery 2014-2015 Microbattery and Capacitor Selection Check Sheet CHECK SHEET If you are considering the purchase of one or more of our microbatteries or capacitors, please complete this check sheet and send it to us. We will let you know which products will be optimum for you to use. Fax Sheet Micro-Energy Division Sales Sec. +81-43-211-8034 Battery Sales Person 1. Your company name 2. Which application do you use? 3. Your expected backup period hour / day / month 4. Your requested delivery date mm / yy 5. Operation voltage of the device for backup 6. Consumption current at backup time V to mA V A * 7. Setting value of charging voltage V 8. Presence of reverse current protection diode 9. Vf characteristics of the reverse current protection diode (at 10A) 10. Resistance value of charging protection resistance Yes * No V W 11. Limit of charging time 12. Required cycle life times 13. Other requests 14. Expected life (e.g., xx years or backup for xx hours) 15. Ambient temperature and humidity Your contact information Name Section Phone Fax E-mail Micro Battery 2014-2015 19 Environmental Activities Environmental Activities at Micro-Energy Division Environment & Quality Policy Seiko Instruments Inc., Micro-Energy Division is located in Ayashi, a city with beautiful nature, in Miyagi Prefecture. Our aim is to provide customer satisfaction and harmony with the environment through all our products, from Micro battery to other electronic products, and sales activities. 1. We adhere firmly to laws, regulations and customers' specified requirements. 2. We aim to prevent pollution, to reduce CO2, and to conserve biodiversity. 3. We set goals, take actions, conduct regular reviews, and improve the system and performance continuously. 4. We contribute to the society by supporting green procurement, developing green products, and promoting green life activity. 5. We adhere to regulations and recommodations regarding Chemical substance content in our products and will promote reduction and replacement. 6. We vigorously educate ourselves and try to engage voluntarily in green life activity. Based on the above policy, the following six environmental approaches are now being implemented throughout Micro-Energy Division. 1. Enrich the line up of Eco-Products * We introduced the SII Green Product Label System which is equivalent to the ISO 14021 Type II environmental label. At the end of FY2006, 100% of our products are certified as SII Green Products. In addition, 38 products are certified as SII "High Grade" Green Products. 2. Reduction of Greenhouse Gas * We practice various CO2 reduction measures like using Eco-machinery. Since 1997, we have successfully reduced a total of 54,100 tons of CO2. We believe our efforts contribute to the prevention of global warming. ton CO2 70,000 Reduction amount of CO2 (accumulated since 1997) 60,000 50,000 40,000 30,000 20,000 10,000 0 97 98 99 00 01 02 03 04 05 06 07 08 09 10 11 12 13 14 target Result 3. 3R Promotion Activity * We have promoted the "reduce and reuse" activities and also promoted recycling at the end of the production process. With these activities, we achieved "Zero-emission" in 2004. We have reduced the non-recyclable wastes to less than 1 ton - less than 1% of our 1997 results. ton 80 Final amount of waste 70 60 50 40 30 20 10 0 97 98 99 00 01 02 03 04 05 06 07 08 09 10 11 12 Result 13 14 target 4. Biodiversity Conservation * We endeavor to deepen our understanding on the relevancy between biodiversity and our business activities, and to contribute to the conservation of biodiversity by participating local community activities. 5. Green Purchasing * We adhere to a green purchasing campaign through the purchase of ingredients, manufacturing materials, and other necessary products, whenever appropriate. 6. Green Life * With the participation of all of Micro-Energy Division members, we deploy a clean-up and beautification campaign in all areas surrounding our factory once a year. In addition, we participate in the clean up activity at Hirose River once a year. 7. Conflict Minerals * Recognizing the international importance of conflict minerals issue, we prohibit the use of such minerals. 20 Micro Battery 2014-2015 Precautions for Your Safety Micro-Energy Division Lithium rechargeable batteries (MS, TS) contain flammable organic solvents. For your safety, please follow the following precautions. WARNING! * Do not charge by higher current or higher voltage than specified. Doing so may generate gas inside the battery, resulting swelling, fire, heat generation or bursting. * Do not heat, disassemble nor dispose of in fire Doing so damages the insulation materials and may cause fire, heat generation, leakage or bursting. * Do not solder directly to the battery If soldering is performed directly to the battery, the battery is heated up, consequently causing leakage, explosion or fire due to overheating from internal short-circuit. * Do not short. If the (+) and (-) come into contact with metal materials, short-circuit occurs. As a result, fire, heat generation, leakage or bursting may occur. * Keep batteries out of children's reach. It is dangerous that children swallow the battery. When you design mechanical hardware around the battery, please fix the battery firmly in order to prevent children from removing it. When you store the batteries, please keep the batteries out of children's reach. If a battery is swallowed, consult a physician immediately. * Do not reverse placement of (+) and (-) * Do not weld terminals to the battery The heat by welding may cause fire, heat generation, leakage or bursting. We weld standard terminals under strictly controlled conditions. If you need to weld terminals to the battery, please consult us in advance. * Do not discharge by force If the battery is discharged by direct connection to an external power supply etc., voltage of the battery will decline lower than 0 volts (electrical reversal) and will cause the battery case to expand, overheat, leak, explode or burn. * In case of leakage or a strange smell, keep away from fire to prevent ignition of any leaked electrolyte. * In case of disposal, insulate between (+) and (-) of battery by an insulating material. Jumbling batteries or with other metal materials cause short-circuit. As a result, fire, heat generation, leakage or bursting may occur. Do not jumble batteries Short-circuiting Example Example of insulation If the (+)and(-) side of the battery is reverse inserted, it may cause a short-circuit or over discharge of the battery on some equipment and it may induce overheating, explosion or fire. Insulating tape discharge discharge Contacting between batteries cause short-circuiting such as above diagram. CAUTION! * If leaked liquid gets in the eyes, wash them with clean water and consult a physician immediately. * Do not use new and used batteries together. Do not use different types of batteries together. * Avoid contact with water. * If you connect two or more batteries in series or parallel, please consult us in advance. * Keep batteries away from direct sunlight, high temperature and humidity. It may cause fire, heat generation, leakage or bursting. It may cause bursting or fire due to unbalanced load or voltage. * Do not use nor leave the batteries in direct sunlight nor in high-temperature areas. * Do not apply strong pressure to the batteries nor handle roughly. It may cause fire, heat generation, leakage or bursting. It may cause heat generation. It may cause heat generation or performance deterioration. It may cause fire, heat generation, leakage or bursting. For prevention of performance deterioration of battery * Pay attention to mat or sheet for ESD Battery with tabs or battery on PCB may short-circuit on the mat for ESD. As a result the voltage of the cell is reduced. * Pay attention to soldering by tips Do no touch the battery by solder chips, when soldering another components after equipping battery. Keep any high temperature process away from battery. * Pay attention to material of jig for pick and place Use non-conductive material of jig for pick and place of batteries, for short-circuit protect. If short-circuit of battery occurs, the voltage of battery drops down quickly but raises gradually. * Pay attention to washing and drying Some detergent or high temperature drying may cause deteriorate of battery. If you need to wash batteries, consult us. International Transportation and Disposal International Air/Marine/Ground Transportation Regarding the transport of Lithium battery, organizations like IATA, ICAO, IMO, DOT have determined transport regulations, based on the United Nations Regulations. The SII Lithium rechargeable batteries can be transported being not subject to the provisions of dangerous goods, if they meet the following requirements. (a) Lithium battery handling label (IATA Dangerous Goods Regulations Figure 7.4.I) must be put on each package. (b) Each shipment must be accompanied with a document indicating that the packages contain Lithium batteries, that the packages must be handled with care, and that special procedures should be followed in the event the package is damaged, and a telephone number for additional information. Micro Battery 2014-2015 (c) Except in the case of packed with equipment, package may not exceed 2.5 kg gross mass. (d) Batteries are separated so as to prevent short-circuit and are packed in strong packaging. (e) Each packages is capable of withstanding a 1.2m drop test in any orientation without damage to batteries contained. For further information, please consult with us. Disposal Recent environment protection concerns have increased globally and waste and recycling are regulated in the world. The current regulations differ in each country, state and local municipality. Please consult local regulations and authorities for recommended disposal of batteries. If you are in question of application or safety of our batteries, please consult your local authorities. 21 Precautions for Your Safety Micro-Energy Division capacitors (XH, CPH, CPX) contain flammable organic solvents. For your safety, please follow the following precautions. WARNING! * Do not charge by higher current or higher voltage than specified. Doing so may generate gas inside the capacitor, resulting in swelling, fire, heat generation or bursting. * Do not reverse placement of (+) and (-) SII capacitors have polarity. If the (+) and (-) side of the capacitor is reverse inserted, it may cause short-circuit or over discharge of the capacitor on some equipment and it may induce overheating, explosion or fire. * Do not solder directly to the capacitor (for XH only) If soldering is performed directly to the capacitor, the capacitor will over heat and, consequently cause leakage, explosion or fire due to overheating from internal short-circuit. * Keep capacitors out of children's reach. It is dangerous that children swallow the capacitor. When you design mechanical hardware around the capacitor, please fix the capacitor firmly in order to prevent children from removing it. When you store the capacitors, please keep the capacitors out of children's reach. If a capacitor is swallowed, consult a physician immediately. * Do not heat, disassemble nor dispose of in fire Doing so damages the insulation materials and may cause fire, heat generation, leakage or bursting. * Do not discharge by force If the capacitor is discharged by direct connection to an external power supply etc., voltage of the capacitor will decline lower than 0 volts (electrical reversal) and will cause the capacitor case to expand, overheat, leak, explode or burn. * In case of leakage or a strange smell, keep away from fire to prevent ignition of any leaked electrolyte. CAUTION! * If leaked liquid gets in the eyes, wash them with clean water and consult a physician immediately. * Do not use nor leave the capacitors in direct sunlight nor in high-temperature areas. It may cause fire, heat generation, leakage or bursting. * Do not make the capacitor airtight by sealing it with adhesive agent or coating agent. It may cause short-circuit because of generated and accumulated electrolyte gas. * Do not use new and used capacitors together. Do not use different types of capacitors together. It may cause fire, heat generation, leakage or bursting. * If you connect two or more capacitors in series or parallel, please consult us in advance. It may cause bursting or fire due to unbalanced load or voltage. * Keep capacitors away from direct sunlight, high temperature and humidity. It may cause heat generation or performance deterioration. All data, dimensions, characteristics and values shown in this catalogue are for reference only. Please contact your local Seiko Instruments Representative for current detailed specifications. IMPORTANT 1. The information herein is subject to change without notice. 2. Neither reproduction, duplication nor unauthorized use of this catalog in whole or part is allowed without the prior written approval of Seiko Instruments Inc. 3. The colors of the products reproduced herein ("Products") may be different from the actual colors. Check colors on actual products before using the Products. 4. Circuits and respective application methods described herein are for reference only. Seiko Instruments Inc. shall not be liable for any damages or losses resulting from any claim by third parties that any Products or application methods described herein infringe any right intellectual property right. All intellectual property rights with respect to the Products belong exclusively to 22 Seiko Instruments Inc. Seiko Instruments Inc. does not grant users of the Products any right or license to the Products hereunder. 5. When Products include Strategic Products (or Services) stipulated in the Foreign Exchange and Trade Control Law, they shall not be exported without permission of governmental authorities. 6. The Products are designed for consumer equipment and cannot be used as part of any device or equipment which influences the human body or requires a significantly high reliability, such as physical exercise equipment, medical equipment, disaster prevention equipment, gas related equipment, vehicles, aircraft and equipment mounted on vehicles without our prior express written consent. Micro Battery 2014-2015 Silver Oxide Battery: is our trademark for silver oxide battery globally acknowledged in the quartz watch market. Low Drain Battery Model Characteristics (RT) C.C.V. 2* Dimensions JIS code IEC code Nominal Voltage (V) Standard 1* Capacity (mAh) Standard Discharge Current (A) SR416SW 337 1.55 7.5 10 4.8 1.65 SR421SW 348 1.55 12 20 4.8 2.15 SR512SW 335 1.55 5.5 5 5.8 SR516SW 317 1.55 12.5 20 20 30 Diameter (mm) Height (mm) Weight (g) at 24 V at -10 V 0.11 1.35 1.10 0.14 1.35 1.10 1.25 0.15 1.45 1.10 5.8 1.65 0.18 1.45 1.10 5.8 2.15 0.23 1.45 1.10 SR521SW 379 1.55 13 16 SR527SW 319 1.55 22 40 5.8 2.70 0.29 1.45 1.10 SR616SW 321 1.55 16 20 6.8 1.65 0.25 1.45 1.10 30 40 6.8 2.15 0.32 1.45 1.20 SR621SW 364 1.55 21 23 SR626SW 377 1.55 24 28 30 30 40 40 6.8 2.60 0.39 1.45 1.20 SR712SW 346 1.55 10 10 7.9 1.25 0.26 1.45 1.20 SR716SW 315 1.55 21 30 7.9 1.65 0.33 1.45 1.20 40 40 7.9 2.10 0.42 1.45 1.20 SR721SW 362 1.55 23 28 SR726SW 397 1.55 34 40 7.9 2.60 0.52 1.45 1.20 SR731SW 329 1.55 36 50 7.9 3.10 0.56 1.45 1.20 SR41SW 384 1.55 45 50 7.9 3.60 0.67 1.45 1.20 SR916SW 373 1.55 27 50 9.5 1.65 0.51 1.45 1.20 60 50 9.5 2.05 0.60 1.45 1.20 SR920SW 371 1.55 46 35 SR927SW 395 1.55 53 60 80 100 9.5 2.70 0.75 1.45 1.20 SR936SW 394 1.55 85 140 9.5 3.60 1.10 1.45 1.20 SR1120SW 381 1.55 53 80 11.6 2.05 0.93 1.45 1.20 SR1130SW 390 1.55 80 100 11.6 3.05 1.29 1.45 1.20 SR43SW 301 1.55 120 150 11.6 4.20 1.75 1.45 1.20 SR44SW 303 1.55 160 180 11.6 5.40 2.20 1.45 1.20 1* The standard capacity is calculated by the measurement result of discharging time with the standard discharge current to the voltage 1.2V. 2* C.C.V.: Closed Circuit Voltage / Low Drain 2k 7.8msec Pulse High Drain Battery Model Characteristics (RT) JIS code IEC code Nominal Voltage (V) Standard 1* Capacity (mAh) Standard Discharge Current (A) Diameter (mm) Height (mm) SR626W 376 1.55 28 50 6.8 2.60 SR721W 361 1.55 26 50 7.9 2.10 SR726W 396 1.55 34 50 7.9 SR41W 392 1.55 45 80 7.9 SR920W 370 1.55 42 80 SR927W 399 1.55 53 60 SR1120W 391 1.55 SR1130W 389 SR43W 386 357 SR44Wphone Cellular C.C.V. 3* Dimensions Weight (g) at 24 V at -10 V 0.39 1.35 0.95 0.41 1.35 1.05 2.60 0.52 1.35 1.05 3.60 0.67 1.35 1.05 9.5 2.05 0.60 1.40 1.00 90 110 9.5 2.70 0.75 1.40 1.05 53 90 11.6 2.05 0.93 1.40 1.20 1.55 80 130 11.6 3.05 1.29 1.40 1.20 1.55 120 220 11.6 4.20 1.75 1.40 1.20 1.55 160 250 11.6 5.40 2.20 1.40 1* The standard capacity is calculated by the measurement result of discharging time with the standard discharge current to the voltage 1.2V. 3* C.C.V.: Closed Circuit Voltage / High Drain 200 5sec DC Micro Battery 2014-2015 1.20 TV 23 Micro-Energy Division who manufactures the products described in this catalog holds the ISO 9001 quality management system certificate, and the ISO 14001 environmental management systems certificate. www.sii-me.com Micro-Energy Division 1-8, Nakase, Mihamaku, Chiba-shi, Chiba 261-8507, Japan Telephone:+81-43-211-1735 Facsimile:+81-43-211-8034 Asia 4-5/F, Wyler Centre 2, 200 Tai Lin Pai Rd., Kwai Chung, N.T., Kowloon, Hong Kong Telephone: +852-2494-5111 Facsimile: +852-2480-5479 Email:sales@sih.com.hk http://www.sih.com.hk 12F, No.101, Sec.2, Nanking E. Rd., Taipei 104, Taiwan, R.O.C. Telephone: +886-2-2563-5001 Facsimile: +886-2-2563-5580 Email:public@sii.co.jp http://www.sii.com.tw Room 2701-2703, 27th Floor, Shanghai Plaza, 138 Mid Huaihai Rd., Shanghai 200021, China Telephone: +86-21-6375-6611 Facsimile: +86-21-6375-6727 #507, 508, Korea City Air Terminal Bldg., 159-6, Samsung-dong, Gangnam-gu, Seoul, 135-728 Korea Telephone: +82-2-565-8006 Facsimile: +82-2-565-8306 http://www.sii.co.kr North/Central/South America Europe Siemensstrasse 9 D-63263 Neu Isenburg, Germany Telephone: +49-6102-297-0 Facsimile: +49-6102-297-50100 Email:info@seiko-instruments.de http://www.seiko-instruments.de 21221 S. Western Ave., Suite 250, Torrance, CA 90501, U.S.A. Telephone: +1-310-517-7802 Facsimile: +1-310-517-7792 Email:info@seikoinstruments.com http://www.sii-me.com Contact us (Specifications are subject to change without notice.) Released in September 2014 Printed with soy ink. Copyright(c)2014 Seiko Instruments Inc. All Right Reserved. No.BAC3011EJ-01C1409