Safety Data Sheet according to (EC) No 1907/2006 - ISO 11014-1 Page 1 of 5 sds no. : 181481 V004.0 MM01921 Tinner Cleaner Revision: 20.05.2010 printing date: 16.08.2011 1. Identification of the substance/preparation and of the company/undertaking Trade name: MM01921 Tinner Cleaner Intended use: Tip Tinner/Cleaner Company name: Henkel Limited 2 Bishop Square Business Park AL109EY Herfordshire Hatfield Great Britain Phone: Fax-no.: +44 1606 593933 +44 1606 863762 E-mail address of person responsible for Safety Data Sheet: ua-productsafety.uk@uk.henkel.com Emergency information: 24 Hours Emergency Tel: +44 (0)1442 278497 2. Hazards identification Fumes evolved at soldering temperatures will irritate the nose, throat and lungs. 3. Composition / information on ingredients Declaration of ingredients according to (EC) No 1907/2006: Hazardous components CAS-No. Tin 7440-31-5 Citric acid 77-92-9 Silver 7440-22-4 Copper 7440-50-8 EINECS ELINCS 231-141-8 content Classification 40 - 50 % 201-069-1 5 - 10 % Xi - Irritant; R36 231-131-3 0,1 - 1 % No classification required. 231-159-6 0,1 - 1 % R52/53 Xn - Harmful; R22 Xi - Irritant; R36/37/38 For full text of the R-Phrases indicated by codes see section 16 'Other Information'. Substances without classification may have community workplace exposure limits available. 4. First aid measures MSDS-No.: 181481 V004.0 MM01921 Tinner Cleaner Inhalation: Move to fresh air. If symptoms persist, seek medical advice. Skin contact: Rinse with running water and soap. Obtain medical attention if irritation persists. Eye contact: Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Seek medical advice. Ingestion: Do not induce vomiting. Seek medical advice. 5. Fire fighting measures Combustion behaviour: The product itself does not burn. Any fire extinguishing action should be appropriate to the surroundings. Special protection equipment for firefighters: Wear self-contained breathing apparatus. Hazardous combustion products: High temperatures may produce heavy metal dust, fumes or vapours. 6. Accidental release measures Environmental precautions: Do not let product enter drains. Clean-up methods: Scrape up spilled material and place in a closed container for disposal. 7. Handling and storage Handling: Use only in well-ventilated areas. Avoid skin and eye contact. Storage: Store in a cool place in closed original container. Page 2 of 5 MSDS-No.: 181481 V004.0 MM01921 Tinner Cleaner Page 3 of 5 8. Exposure controls / personal protection Components with specific control parameters for workplace: Valid for Great Britain Basis UK EH40 WELs Ingredient ppm TIN (INORGANIC COMPOUNDS AS SN) 7440-31-5 SILVER (METALLIC) 7440-22-4 SILVER, METALLIC 7440-22-4 COPPER, INHALABLE DUSTS AND MISTS (AS CU) 7440-50-8 COPPER, FUME 7440-50-8 COPPER, INHALABLE DUSTS AND MISTS (AS CU) 7440-50-8 mg/m3 2 Type Time Weighted Average (TWA). Time Weighted Average (TWA). Time Weighted Average (TWA). Short Term Exposure Limit (STEL): 0,1 0,1 2 0,2 Time Weighted Average (TWA). Time Weighted Average (TWA). 1 Category Indicative Remarks ECTLV EH40 WEL Indicative ECTLV EH40 WEL EH40 WEL EH40 WEL Engineering controls: Ensure adequate ventilation, especially in confined areas. Extraction is necessary to remove fumes evolved during reflow. Where reasonably practicable this should be achieved by the use of local exhaust ventilation and good general extraction. Respiratory protection: In case of insufficient ventilation, wear suitable respiratory equipment. Hand protection: For hand protection, use rubber or plastic gloves. Eye protection: Wear protective glasses. 9. Physical and chemical properties General characteristics: Appearance Paste Grey Mild Odor: Phys./chem. properties: pH-value Boiling point Flash point Vapor pressure Density () Solubility (qualitative) (Solvent: Water) Melting point VOC content (1999/13/EC) not applicable Not determined none Not determined 3,5 g/cm3 Insoluble 217 C (422.6 F) < 1,00 % 10. Stability and reactivity Conditions to avoid: Stable under normal conditions of storage and use. MSDS-No.: 181481 V004.0 MM01921 Tinner Cleaner Page 4 of 5 Materials to avoid: Solder alloy will react with concentrated nitric acid to produce toxic fumes of nitrogen oxides. Hazardous decomposition products: Thermal decomposition can lead to release of irritating gases and vapors. 11. Toxicological information Oral toxicity: May cause irritation to the digestive tract. Inhalative toxicity: Fumes evolved at soldering temperatures will irritate the nose, throat and lungs. Skin irritation: Prolonged or repeated contact may cause skin irritation. Eye irritation: Prolonged or repeated contact may cause eye irritation. Fumes emitted during soldering may irritate the eyes. 12. Ecological information Persistence and Biodegradability: The product is not biodegradable. Ecotoxicity: Hazardous components CAS-No. Copper 7440-50-8 Species Bluegill (Lepomis macrochirus) General ecological information: Do not empty into drains / surface water / ground water. 13. Disposal considerations Product disposal: Wherever possible unwanted solder alloy should be recycled for recovery of metal. Waste code(EWC ): 06 04 05 - wastes containing other heavy metals Disposal of uncleaned packages: Dispose of as unused product. 14. Transport information General information: Not hazardous according to RID, ADR, ADNR, IMDG, IATA-DGR. Exposure Value time type 96 h LC 50 Value 10 mg/l MSDS-No.: 181481 V004.0 MM01921 Tinner Cleaner Page 5 of 5 15. Regulations - classification and identification Indication of danger: none Risk phrases: Not classified as hazardous. Safety phrases: not applicable Additional information: Avoid breathing fumes given out during soldering. Flux fumes may irritate the nose, throat and lungs and may after prolonged/repeated exposure give an allergic reaction (asthma). After handling solder wash hands with soap and water before eating, drinking or smoking. Keep out of reach of children. Additional labeling: Safety data sheet available for professional user on request. National regulations/information (Great Britain): Remarks The Health & Safety at Work Act 1974. The Control of Substances Hazardous to Health Regulations. L5:General Approved Code of Practice to the COSHH Regulations. HS(G)97:A Step by Step Guide to the COSHH Regulations. HS(G)193:COSHH essentials: Easy steps to control chemicals. 16. Other information The labelling of the product is indicated in Section 15. The full text of the R-phrases indicted by codes in this safety data sheet are as follows: R22 Harmful if swallowed. R36 Irritating to eyes. R36/37/38 Irritating to eyes, respiratory system and skin. R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Further information: This information is based on our current level of knowledge and relates to the product in the state in which it is delivered. It is intended to describe our products from the point of view of safety requirements and is not intended to guarantee any particular properties. This safety data sheet was prepared in accordance with Council Directive 67/548/EEC and it's subsequent amendments, and Commission Directive 1999/45/EC.