Technical Data March 2015 3MTM Thermal Bonding Film 583 Product Description 3MTM Thermal Bonding Film 583 is a high strength, flexible, nitrile phenolic based thermoplastic bonding film. It can be heat or solvent activated for bonding. This film can also be lightly crosslinked using a post heat exposure. This crosslinking will provide additional heat and solvent resistance as well as somewhat higher shear strengths. 3M TBF 583 must be stored at or below 4C (40F) for maximum storage life. Key Features * Flexible *Slight surface tack *Heat or solvent activation *Heat crosslinkable option *Can be die-cut * Lower temperature lamination of the nitrile phenolic film range Typical Physical Properties Note: T he following technical information and data should be considered representative or typical only and should not be used for specification purposes. Product 3MTM Thermal Bonding Film 583 Base Resin Nitrile phenolic Adhesive Thickness 2 mil (0.05 mm) Tack Slight Color Brown Construction 2 mil adhesive 3 mil silicone paper liner Before Crosslinking After Crosslinking Tensile (psi) 400 3,140 Elongation (%) 800 180 Modulus (psi) 240 13,800 71C (160F) >149C (300F) 2 Lb. Dead Load Overlap Shear Heat Resistance *Tensile and elongation conducted on Sintech 5/GL at 0.2"/minute speed. ASTM D638. *2 lb. dead load overlap shear conducted in oven environment (reference ASTM D4502-85). 3MTM Thermal Bonding Film 583 Application Equipment Suggestions Note: Appropriate application equipment can enhance bonding film performance. We suggest the following equipment for the user's evaluation in light of the user's particular purpose and method of application. The type of application equipment used to bond 3MTM Thermal Bonding Film 583 will depend on the application involved and on the type of equipment available to the user. Thin films and flexible substrates can be bonded using a heated roll laminator where heat and pressure can be varied to suit the application. Larger, thicker substrates can be bonded using a heated static press or, in some cases, an autoclave. For applications where a shaped adhesive is to be transferred to a flat or three-dimensional part, a hot shoe or thermode method may be appropriate. It is recommended that whatever method of bonding is chosen by the user, the optimum bonding conditions should be predetermined with substrates specific to user's application. Directions For Use - Heat Activation To make a bond, remove the liner and place the adhesive film between the two substrates. The bond is then made through heat and pressure using a heated press, a hot roll laminator, a hot shoe thermode method or similar equipment. Alternatively, the adhesive can be first tacked (lightly bonded) to one of the substrates using low heat, the liner can then be removed and second substrate placed to the exposed adhesive surface, and a bond made using heat and pressure. Since 3M TBF 583 has a slight surface tack, in some cases it may be tacked to a substrate with pressure only (no heat). Suggested TACKING Conditions 38C to 49C (100F to 120F) bondline temperature 2-5 seconds dwell time 5-20 psi pressure For optimum bonding, the heat, pressure and dwell time for using 3M TBF 583 will depend upon the type and thickness of the substrates being bonded together. A suggested starting point, however, is to use the bonding conditions described below. Suggested BEGINNING Bonding Conditions 107C to 149C (225F to 300F) bondline temperature 2-5 seconds dwell time 15-20 psi pressure (2) 3MTM Thermal Bonding Film 583 Directions For Use - Heat Activation (continued) One approach to establishing the correct/optimum bonding conditions for a user's application is to evaluate a series of bonding temperatures, for example 93, 107, 121, 135 and 149C (200, 225, 250, 275 and 300F). Time and pressure will be dictated by the thickness of the substrate and the type of substrate being bonded. Thicker substrates and surfaces that may be more difficult to bond will require longer times, higher pressures and higher temperatures. If voids are experienced in the bondline, they can be minimized by increasing pressure. Once the bond is made, the bondline should be allowed to cool somewhat before stress is applied to the bond. Generally, cooling the bondline below 66C (150F) is adequate to allow the bonded parts to be unfixtured/unclamped and handled. For reference, the following table shows typical bond strengths for bonds made at various temperatures. Such data can be used to evaluate optimum bondline temperatures. It is important to note that this table is valid only for the specific substrates shown. Varying temperature, pressure, or substrates can affect bond strengths. User should develop a similar table with substrates specific to user's application. Note: Temperatures shown are bondline temperatures and not heat block or roll settings! 90 Peel Strengths of Bonds made at Various Temperatures (2 and 20 sec. Dwell at Bondline Temperature) using 3MTM Thermal Bonding Film 583 Bondline Temperature FR-4 / Aluminum 2 sec. 20 sec. CRS / Aluminum 2 sec. 20 sec. 24C (75F) 9 piw 9 piw 5 piw 6 piw 35C (95C) 9 piw 9 piw 6 piw 6 piw 46C (115) 9 piw 9 piw 6 piw 6 piw 57C (135F) 10 piw 10 piw 6 piw 7 piw 68C (155F) 11 piw 11 piw 7 piw 9 piw 79C (175F) 12 piw 13 piw 8 piw 10 piw 90C (195F) 13 piw 14 piw 9 piw 12 piw 101C (215F) 14 piw 14 piw 11 piw 14 piw 113C (235F) 14 piw 13 piw 12 piw 13 piw 124C (255F) 12 piw 12 piw 13 piw 13 piw 135C (275F) 12 piw 12 piw 12 piw 12 piw 146C (295F) 12 piw 11 piw 12 piw 12 piw 157C (315F) 11 piw 11 piw 11 piw 12 piw 168C (335F) 11 piw 11 piw 10 piw 11 piw 179C (355F) 11 piw 10 piw 6 piw 9 piw *Peel values given in piw (pounds per inch width). ASTM D1876. *Peel bonds were 1/2" wide using 4 mil etched aluminum bonded to either FR-4 printed circuit board substrate (alcohol wiped) or cold rolled steel (MEK wiped).* Bonds made on Sencorp device using 20 lbs. pressure. *Note: When using solvents, extinguish all ignition sources and follow the manufacturer's precautions and directions for use. (3) 3MTM Thermal Bonding Film 583 Directions For Use - Solvent Activation There are advantages and disadvantages with heat and solvent activation. Under normal conditions, heat activation is the suggested method of bonding and will provide the greatest immediate adhesion strength. However, solvents such as MEK, toluene and/or acetone can also be used to activate bonding if user is working with substrates that are heat-sensitive or have irregular surface or shape.* The solvent may be applied to the film by brushing, wiping, spraying or dipping. It is important that the solvent be allowed sufficient activating time to solvate the adhesive and bring it to a tacky, pressure sensitive state (typically 10-30 seconds). Adhesive legs should appear during touch-testing before substrate is bonded. Bonding should occur before tackiness disappears. If film is too wet, substrate may slip from bonding position; if too dry, a good bond may not develop. When a solvent activation method is used, maximum adhesion strength will not be achieved immediately because it will be related to the drying time of solvent from the adhesive. If the bond undergoes natural drying in ambient temperatures, bond build-up may continue for 30 days until maximum adhesion is achieved. If the bond is exposed to constant low heat (~66C/150F) after initial solvent activation, maximum adhesion can often be reached within 24-30 hours. *Note: W hen using solvents, extinguish all ignition sources and follow the manufacturer's precautions and directions for use. Directions For Use - Crosslinking 3MTM Thermal Bonding Film 583 may also be slightly crosslinked to enhance adhesion performance. Crosslinking of this film can typically be achieved by heating the bondline at 177C (350F) for five minutes. Note: All reported data has not undergone crosslinking unless otherwise stated. (4) 3MTM Thermal Bonding Film 583 Typical Performance Characteristics Note: T he following technical information and data should be considered representative or typical only and should not be used for specification purposes. Test Substrate Adhesion to Various Substrates Using 3MTM Thermal Bonding Film 583 Overlap Shear (OLS) 90 Peel Aluminum (solvent wiped) 580 psi 10 piw Aluminum (etched) 630 psi 10 piw Aluminum (sanded, solvent wiped) 640 psi 10 piw Aluminum (scour pad abraded, solvent wiped) 660 psi 10 piw FR-4 (printed circuit board substrate) 600 psi 11 piw Phenolic Board 500 psi 9 piw Cold Rolled Steel 750 psi 11 piw Stainless Steel NT 10 piw ABS (acrylonitrile-butadiene-styrene) NT 10 piw Ultem 1000 (polyetherimide) NT 10 piw Soda Lime Glass NT 9 piw PVC (polyvinyl chloride) NT 10 piw Acrylic NT 10 piw Polypropylene NT <1 piw HDPE (high density polyethylene) NT <1 piw HIPS (high intensity polystyrene) NT 9 piw EPDM (ethylene-propylene-diene monomer rubber) NT Neoprene (Shore A60) NT 6 piw Nitrile (Shore A60) NT 7 piw SBR (styrene butadiene resin) NT DuPontTM Kapton(R) 200E (polyimide film) NT 5 piw PET (polyester film) NT 3 piw PEN (polyethylene naphthalate film) NT 2 piw Denim Fabric NT 8 piw <1 piw 16 piw *"NT" represents "Not Tested". *OLS values given in psi (pounds per square inch). ASTM D1002. Peel values given in piw (pounds per inch width). ASTM D1876. *OLS bonds were 1" x 1" using 20 mil etched aluminum bonded to each test substrate. Sintech 5/GL shear rate was 0.2"/minute. *Peel bonds were 1/2" wide using 4 mil etched aluminum bonded to each test substrate. Sintech 5/GL peel rate was 2"/minute. *Solvent wiped (MEK or alcohol)*; 3MTM Scotch-BriteTM Scour Pad (green) abraded; sanded (500 grit sandpaper). *Samples were bonded on Sencorp device for 5 seconds dwell (+10 seconds ramp time) at 157C (315F), 20 pounds pressure. *Note: When using solvents, extinguish all ignition sources and follow the manufacturer's precautions and directions for use. (5) 3MTM Thermal Bonding Film 583 Typical Performance Characteristics (continued) Note: T he following technical information and data should be considered representative or typical only and should not be used for specification purposes. Adhesion Strength after Environmental Aging using 3MTM Thermal Bonding Film 583 Overlap Shear 90 Peel Aging Pameters FR-4 / FR-4 FR-4 / Aluminum 30 days at room temperature (control) 810 psi 12 piw 30 days at 71C (160F) oven 780 psi 8 piw 30 days at 49C (120F) oven/100% RH 730 psi 13 piw 30 days immersion in distilled water 770 psi 10 piw *OLS values given in psi (pounds per square inch). ASTM D1002. Peel values given in piw (pounds per inch width). ASTM D1876. *OLS bonds were 1" x 1" using FR-4 printed circuit board substrate bonded to FR-4 (alcohol wiped).* Sintech 5/GL shear rate was 0.2"/minute. *OLS samples were oven bonded at 157C (315F) for 30 minutes. Sample was clamped between 63 mil aluminum using two #50 binder clips during bonding process. *Peel bonds were 1/2" wide using 4 mil etched aluminum bonded to FR-4 (alcohol wiped). Sintech 5/GL peel rate was 2"/minute. *Peel samples were bonded on Sencorp device for 5 seconds dwell (+10 seconds ramp time) at 157C (315F), 15 pounds pressure. *Note: When using solvents, extinguish all ignition sources and follow the manufacturer's precautions and directions for use. Adhesion Strength TESTED at Various Temperatures using 3MTM Thermal Bonding Film 583 Test Temperature OVERLAP SHEAR FR-4 / Aluminum CRS / Aluminum No X-link X-linked No X-link X-linked -55C (-67F) 600 psi 24C (75F) 650 psi 121C (250F) 40 psi Test Temperature 380 psi 740 psi 860 psi 680 psi 270 psi 7 psi 670 psi 950 psi 170 psi 90 DEGREE PEEL FR-4 / Aluminum CRS / Aluminum No X-link X-linked No X-link X-linked -55C (-67F) 2 psi 24C (75F) 11 psi 121C (250F) 4 psi 1 psi 2 psi 2 psi 9 psi 11 psi 10 psi 5 psi 2 psi 6 psi *OLS values given in psi (pounds per square inch). ASTM D1002. Peel values given in piw (pounds per inch width). ASTM D1876. *OLS bonds were 1" x 1" using either FR-4 printed circuit board (alcohol wiped) or cold rolled steel (MEK wiped)* bonded to 20 mil etched aluminum. Sintech 5/GL shear rate was 0.2"/minute. *Peel bonds were 1/2" wide using either FR-4 printed circuit board (alcohol wiped) or cold rolled steel (MEK wiped) bonded to 4 mil etched aluminum. Sintech 5/GL peel rate was 2"/minute. *Samples not crosslinked ("no x-link") were bonded on Sencorp device for 5 seconds dwell (+10-15 seconds ramp time) at 149C (300F), 20 pounds pressure. *Crosslinked ("x-linked") samples underwent Sencorp bond previously stated, plus oven bond at 177C (350F) (8 minutes ramp time and 5 minutes dwell at temperature). Sample was clamped between 63 mil aluminum using two #50 binder clips during bonding process. *Note: When using solvents, extinguish all ignition sources and follow the manufacturer's precautions and directions for use. (6) 3MTM Thermal Bonding Film 583 3MTM Thermal Bonding Film 583 Bond Graphs BOND STRENGTH BUILD-UP 3MTM THERMAL BONDING FILM 583 lbs/in Solvent activated - T-952-MEK Heat activated - 177C, 344 KPa, 10 sec 20.0 350 Heat Activated - Immediate 18.0 315 16.0 280 Solvent Activated - Heated 24hrs at 150F 14.0 245 12.0 210 10.0 175 N/100mm 8.0 140 Solvent Activated - Natural Drying 5.0 105 4.0 70 2.0 35 24 hrs 48 hrs 72 hrs TIME TYPICAL BOND 3MTM THERMAL BONDING FILM 583 N/100 mm lbs/in 20.0 350 18.0 315 16.0 14.0 280 Typical solvent activation Bond Strength vs. Activation Temperature 245 12.0 210 10.0 175 8.0 140 6.0 105 Test - .008" aluminum to .062" aluminum peel Activation - 50 psi 10 sec. dwell 4.0 70 2.0 35 250 121 260 127 270 132 280 138 290 143 300 149 310 154 320 160 330 166 340 171 Temperature (7) 350 177 360 182 370 188 380 193 390 199 400 204 410 210 3MTM Thermal Bonding Film 583 3MTM Thermal Bonding Film 583 Bond Graphs BOND TYPE 3MTM THERMAL BONDING FILM 583 TIME 120 100 O V E R L A P 90 80 70 NO BOND 60 THERMOPLASTIC BOND O V E R L A P THERMOSET BOND 50 40 30 20 10 100 38 150 65 200 93 250 121 Temperature (8) 300 149 350 177 400F 204C 3MTM Thermal Bonding Film 583 Electrical Data Test Method Before X-Link After X-Link Dielectric Constant @ 1kHz ASTM D-150 3.1 5.7 Dissipation Factor @ 1kHz ASTM D-150 .064 .037 Dielectric Breakdown Strength (volts/mil) ASTM D-149 3000 (on 1.5 mil) 990 (on 8 mil) Surface Resistivity (ohms/sq.) ASTM D-257 3.14 x 1010 3.43 x 1010 Volume Resistivity (ohms-cm.) ASTM D-257 1.44 x 1012 2.13 x 1013 Thermal Data Test Weight Loss by TGA (Thermogravimetric analysis) Coefficient of Thermal Expansion by TMA (Thermomechanical analysis) Tg (extrapolated onset) Method Before X-Link Perkin-Elmer Series 7 1% wt. loss RT to 600C, 10C/min. 5% wt. loss in air 10% wt. loss Perkin-Elmer Series 7 -40C to 125C @ 10C/min. Below Tg CTE/C Above Tg CTE/C After X-Link 159C 274C 352C 260C 318C 371C 280 x 10-6 740 x 10-6 -- 380 x 10-6 (2 heat cycles, 2nd cycle reported) Perkin-Elmer Series 7 -40C to 125C @ 10C/min. 4C 20C Storage Store product at or below 4C (40F) for maximum storage life. Higher temperatures reduce normal storage life. Shelf Life Shelf life is 6 months from date of shipment at 23C (75F) and 18 months from date of shipment at 4C (40F). Important Note Please consult Federal, State, and Local Regulations. State Volatile Organic Compound (VOC) regulations may prohibit the use of certain alcohol solutions or solvents. You should check with your state environmental authorities to determine whether use of a solution or solvent is restricted or prohibited. (9) 3MTM Thermal Bonding Film 583 Regulatory For regulatory information about this product, contact your 3M representative. Technical Information The technical information, recommendations and other statements contained in this document are based upon tests or experience that 3M believes are reliable, but the accuracy or completeness of such information is not guaranteed. Product Use Many factors beyond 3M's control and uniquely within user's knowledge and control can affect the use and performance of a 3M product in a particular application. Given the variety of factors that can affect the use and performance of a 3M product, user is solely responsible for evaluating the 3M product and determining whether it is fit for a particular purpose and suitable for user's method of application. Warranty, Limited Remedy, and Disclaimer Unless an additional warranty is specifically stated on the applicable 3M product packaging or product literature, 3M warrants that each 3M product meets the applicable 3M product specification at the time 3M ships the product. 3M MAKES NO OTHER WARRANTIES OR CONDITIONS, EXPRESS OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OR CONDITION OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR ANY IMPLIED WARRANTY OR CONDITION ARISING OUT OF A COURSE OF DEALING, CUSTOM OR USAGE OF TRADE. If the 3M product does not conform to this warranty, then the sole and exclusive remedy is, at 3M's option, replacement of the 3M product or refund of the purchase price. Limitation of Liability Except where prohibited by law, 3M will not be liable for any loss or damage arising from the 3M product, whether direct, indirect, special, incidental or consequential, regardless of the legal theory asserted, including warranty, contract, negligence or strict liability. Electronics Materials Solutions Division 3M Center, Building 224-3N-11 St. Paul, MN 55144-1000 1-800-251-8634 phone 651-778-4244 fax www.3M.com/electronics 3M and Scotch-Brite are trademarks of 3M Company. DuPont and Kapton are trademarks of E. I. du Pont de Nemours and Company or its affiliates. Please recycle. (c)3M 2015. All rights reserved. 78-9236-7069-5 (10)